pH Flashcards
Acids
Proton donors
Bases
Proton acceptors
pKa
pKa = -logKa
Ka = 10^-pKa
Strong acids
Dissociate completely in water
HCl -><- H+ + Cl-
Weak acids
Partially dissociate in water
CH3COOH -><- H+ + CH3COOH-
Ka
Ka = [H+] [A-] / [HA]
Ka = [H+]^2 / [HA]
If Ka is higher then it is a strong acid. However if it is lower then it is a weak acid.
Assumptions
- [H+] = [A-] – assuming that HA dissociates into H+ and A- equally
- [HA]equ = [HA]start - [H+] equ – assuming that dissociation in weak acids is small so we can neglect any decrease in [HA] from dissociation.
An acid-base indicator
A weak acid (HIn) that changes colour in acidic form and in its conjugate base form
Equivalence point
The point in a titration at which the volume of one solution has reacted exactly with the volume of the second solution
End point
The point in a titration where the indicator contains equal concentrations of its HA and A- forms hence it shows the in-between colour
End point
The point in a titration where the indicator contains equal concentrations of its HA and A- forms hence it shows the in-between colour
End point
The point in a titration where the indicator contains equal concentrations of its HA and A- forms hence it shows the in-between colour