petrochemicals and Organic chemistry Flashcards
what is crude oil
a mixture of hydrocarbons(fossil fuel)
How does fractional distillation work
Oil is heated to about 450 degrees celsius and pumped into to the bottom of the tall tower called the fractionating column, where it vaporizes. The column is very hot at the bottom but much cooler at the top. As the vaporized oil rises, it cools and condenses. Heavy fractions(containing large molecules)have a high boiling point and condense near the bottom of the column. Lighter fractions(containing small molecules) have a lower boiling point and condense further up the column.
Properties of large molecules
- high boiling point
- not volatile
- does not flow easily
- does not ignite easily
Properties of small molecules
- low boiling points
- very volatile
- flows easily
- ignites easily
Why is carbon such a useful atom
Carbon has 4 valence electrons, therefore easily react with other atoms. It can also form multiple bonds to itself and with atoms of other elements. C-C single bonds and C-H bonds are very strong forming materials with high tensile strength a carbon atom can have four covalent bonds and form long chain with itself to produce branched compounds.
Alkanes
general formula: CnH2n+2
functional group: C-C
molecular formula: C2H6(ethane)
examples of alkanes
- ethane(C2H6)
- methane(CH4)
- Propane(C3H8)
- Butane(C4H10)
What are isomers
Structural isomers are compounds with the same molecular formula but different structural formula.
physical properties of alkanes
- unreactive but will undergo combustion(make good fuel)
- soft
- low melting points
Alkenes
general formula: CnH2n
functional group: C=C
Molecular formula: Ethene(C2H4)
some simple alkenes
- methene(CH2)
- propene(C3H6)
- pentene(C5H10)
Breaking long chain alkenes
Fractions that are produced by the distillation of crude oilcan with go the process of cracking, which produces smaller hydrocarbons, including alkanes and alkenes
What occurs during the process of cracking
Fractions containing large hydrocarbons can be vaporized and then passed over a hot catalyst. This breaks the chemical bonds in the molecule and forms smaller hydrocarbon molecules.
alcohols
General formula: CnH2n+1OH
functional group: -OH
Molecular formula: Ethanol(C2H5OH)
Carboxylic acids
General formula: CnH2nO2
Functional group: -COOH
Molecular formula: Ethanoic acid(CH3COOH)
What is a homologous series
A homologous series is a series of compounds that have similar properties and the same general formula
What are monomers/polymers
A monomer is a molecule that is able to bond in long chains.
A polymer can be made up of thousands of monomer. This linking up of monomers is called polymerization.
What is an addition reaction
Addition reactions only occur with unsaturated compounds, that is, compounds containing a carbon-to-carbon double bond or a carbon-to-carbon triple bond. In other words, alkenes or alkynes. Addition reactions of monomers causes polymers to form.
Examples of polymers
- polyethene
- polypropene
- polystyrene
- Teflon
What is the bromine test
Bromine is an orange/brown solution, alkanes have the ability to turn this solution transparent when shaken together, alkenes are unable to do this.
How are esters formed
Esterification= the production of esters by adding an alcohol to a carboxylic acid functional group: O II C / \ R OR