Periodicity Flashcards

1
Q

Define First Ionisation Energy

A

Energy required to remove one electron from each atom in 1 mole of gaseous positive ions

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2
Q

What three factors increase ionisation energy

A

Electron Shielding
Atomic radii
Nuclear charge

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3
Q

What happens to ionisation energy across a period

A

Increases
Nuclear charge increases
Atomic radius decreases
Electron shielding stays the same

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4
Q

What happens to ionisation energy down a group

A

Decreases
Electron shielding increase
atomic radii increases
nuclear charge increases

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5
Q

What is a metallic bond

A

Strong electrostatic attraction between positive metal ions and negative delocalised electrons

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6
Q

Properties of Giant metallic latice

A

High m.p + b.p due to strong electrostatic forces
Insoluble due to strong electrostatic forces
Good conductors as delocalised electrons can move to carry charge

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7
Q

Properties of Giant Covalent Lattice

A

High m.p + b.p due to strong covalent bonds between atoms
Insoluble due to strong covalent bonds
Only graphene and graphite are conductive

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8
Q

What happens to the solubility of Hydroxides from group 2

A

Increases down the group
This means more OH- are present and thus more alkaline

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9
Q

What are the uses of group 2 bases

A

Ca(OH)2 is added to neutralise soil
Mg(OH)2 and Ca(OH)2 are used as antacids

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10
Q

What is the electron configuration of halogens

A

s2 p5

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11
Q

What is the trend in boiling point for halogens

A

Increases as you go down,
more electrons
more london dispersion forces
more energy needed

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12
Q

What is the trend in reactivity for halogens

A

Decreases
Electron shielding increases
Atomic radii increases
Nuclear charge increases
Less nuclear attraction

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13
Q

What colour does bromide form in an organic layer

A

orange

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14
Q

What colour does Iodine form in an organic layer

A

Purple

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15
Q

what is disproportionation

A

When an element has been both oxidised and reduced

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16
Q

What happens when chlorine is added to cold NaOH

A

Cl2 + 2NaOH -> NaClO + NaCl + H2O

17
Q

What is the halide ion test

A

Silver nitrate is added
Cl - white precipitate
Br - cream precipitate
I - yellow precipitate

18
Q

What is the test for carbonate

A

Add dilute nitric acid
if there are bubbles it could be a carbonate as CO2 would be released from the reaction
Bubble it through limewater and if it goes cloudy a carbonate is present

19
Q

Test for sulfate

A

Add Ba2+ (using BaCl2)
SO4 reacts with barium if present
white precipitate forms

20
Q

Test for presence of NH4+

A

Heat with NaOH
NH3 would be produced if NH4 was present
NH3 gas turns pH indicator blue