Periodicity Flashcards

1
Q

On which side are metals found on the periodic table?

A

The left side

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2
Q

On which side are non-metals found on the periodic table?

A

The right side

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3
Q

Where are metalloids found on the periodic table?

A

In the middle

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4
Q

What do metals tend to lose and form?

A

Metals tend to lose electrons and form positive ions.

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5
Q

What happens when an elements loses an electron?

A

Its becomes a positively charged cation

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6
Q

What happens when an elements gains an electron?

A

It becomes a negatively charged anion

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7
Q

What is electron affinity?

A

Electron affinity is when an element in gas phase gains an electron and becomes a negative ion. The higher the electron affinity of an element is, the easier it is to form a negative ion.

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8
Q

Do non metals, metals, or metalloids have higher Electron affinity?

A

Non-metals have a higher EA than metals, and tend to form negative ions (Anions)

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9
Q

Why is it so difficult for group 7 elements to lose an electron?

A

because they are very close to have a stable octet but they will readily accept an electron.

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10
Q

What does it mean if electron affinity have positive values?

A

Positive values of electron affinity means that electrons will not attach themselves
to the atoms. In the case of N, the additional electron will have to pair with another
electron in the 2px orbital – larger electron repulsions!

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11
Q

Why are Ionisation Energy and Electron Affinity important?

A

Elements with low ionisation potential easily give their electrons to elements with high electronic affinity. This forms an ionic bond.

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12
Q

What happens between two elements if ionisation potential is too high or if electronic affinity is too low?

A

If the ionisation potential is too high, and / or the electronic affinity is too low,
they don’t bother becoming ions, and prefer to share their electrons and form a
COVALENT BOND

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13
Q

What is the periodic table based on?

A

The periodic table is based on a set of rules common to the elements which is atomic structure.

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14
Q

How are elements arranged in the periodic table?

A

Elements which have similar chemical properties occur in periodic intervals relative to their respective atomic mass, which is why they are arranged the way they are in the periodic table.

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15
Q

Which elements have lower ionisation energy?

A

Elements on the left side of the periodic table (metals) have low ionisation energy. Elements on the right side of the table (non metals) have the highest ionisation energy.

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16
Q

What are the vertical rows for?

A

Groups

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17
Q

What are placed in groups?

A

-Elements with similar properties are place in groups.

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18
Q

What are horizontal rows for?

A

Periods

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19
Q

What does period number correspond to?

A

-Period number corresponds to the highest occupied energy level.

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20
Q

What are transition elements?

A

elements with incomplete d orbitals

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21
Q

What are representative elements?

A

elements with full inner orbitals but an incomplete outer shell.

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22
Q

Which electrons are the most reactive?

A

Valence electrons.

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23
Q

How to abbreviate electron configs?

A

Watch this:
https://www.youtube.com/watch?v=rmu3kA6VS8c

24
Q

How is the periodic table in elongated form arranged

A

Arranged linearly with respect to atomic number.

25
Q

Why are higher energy levels good?

A

Higher energy levels (shell) = more space for electrons to fill (atomic radii)
> energy level 4 = space for more electrons (d orbitals)
> energy level 6 = space for even more (f orbitals)

26
Q

Why do elements in the same group have the same valency?

A

They have the same outer energy level/electron configurations. Therefore they have the same valency.

27
Q

Why is the periodic table useful?

A

Characteristic properties and trends of the elements allow us to use the periodic table to predict properties and reactions of a variety of substances such as:

  • Metals and nonmetals
  • Atomic volume
  • Ionisation energy
  • Electron affinity
  • Electronegativity
28
Q

Where are metals found on the periodic table?

A

The left

29
Q

Where are non metals found on the periodic table?

A

On the right

30
Q

Why do metals tend to lose electrons?

A

To form positive ions.

31
Q

What are the chemical properties of metals?

A

Metals tend to lose e - and form positive ions

32
Q

What the phyisical properties of metals?

A

▪ lustrous
▪ malleable
▪ good conductors of heat
▪ good conductors of electricity.

33
Q

Chemical properties of non metals?

A

Non-metals tend to gain e- and form negative ions

34
Q

Physical properties of non metals?

A

▪ Non-lustrous
▪ brittle
▪ poor conductors of heat
▪ poor conductors of electricity

35
Q

What is transferred to what when metals react with non-metals?

A

When metals react with nonmetals e - are usually transferred from the metal to the non-metal

36
Q

Properties of metalloids?

A

Metalloids have properties that are intermediate between metals and nonmetals

37
Q

Metallic character increases as…

A

Metallic character increases as you go down a group and from right to left. Metals are also more likely to form positive ions as you go left and down.

38
Q

What are the valence electrons attracted to and repelled by?

A

A valence electron is attracted to the positively charged nucleus, and repelled by other electrons in the atom.

39
Q

What is the function of the inner core electrons in relation to the valence shells attraction to the nucleus?

A

The inner core electrons are effective at partially cancelling the attraction of the valence electron for the nucleus.

The inner core of electrons screen or shield the valence electrons from the positive nuclear charge of the nucleus.

40
Q

What does the screening factor represent?

A

The screening factor (S) represents the number of inner core electrons.

41
Q

What does Z represent?

A

Number of protons

42
Q

Equation for Effective nuclear charge (Zeff)

A

Effective nuclear charge (Zeff) = Z (num of protons) – S (screening factor (number of inner core electrons) ).

43
Q

Zeff Example: Magnesium.

A

Electron configuration = 1s2, 2s2, 2p6, 3s2
The 1s2, 2s2, 2p6 are the core electrons. It has 10 of them.
The 3s2 are the valence electrons.
It has 12 protons since atomic number = num of protons = num of electrons
Effective nuclear charge (Zeff) = 12 – 10 = +2
The valence electrons are both subjected to a nuclear force of +2 – each pulled inwards from the strength of 2 protons

44
Q

What are the valence electrons subjected to in Mg?

A

The valence electrons are both subjected to a nuclear force of +2 – each pulled inwards from the strength of 2 protons

45
Q

What is Effective nuclear charge important for?

A

Important implication for ionisation energy

46
Q

What is ionisation energy?

A

Ionisation energy is the energy required to remove an electron from a (valence) shell.

47
Q

Do elements in the same group all have the same configuration?

A

Yes

48
Q

As we move from one element to another, effective nuclear charge…

A

increases.

49
Q

Why does nuclear charge of elements increase as we go across the periods?

A

The additional valence electrons added to counterbalance the nuclear charge shield each other ineffectively, hence effective nuclear charge increases.

50
Q

What are the trends in atomic volume?

A

Radii of atoms increase down a group
This is due to the quantum (electrons) number increasing (n) i.e.
The outer electrons are further away from the nucleus
Radii of atoms tend to decrease from left to right across a period
Each time an electron is added, a proton is added to the nucleus.
This increases the positive effective nuclear charge (Zeff) which pulls all the electrons closer to the nucleus

51
Q

In general, smaller atoms have…

A

In general, smaller atoms have higher ionisation energies

52
Q

What does ionisation energy depend on?

A

IE depends on Zeff and the average distance of the electron from the nucleus

53
Q

What happens when you decrease the distance of the electron from the nucleus?

A

Decreasing the distance of the electron from the nucleus or increasing Zeff increases ionisation energy.

54
Q

Do metals or non metals have lower IE (ionisation energy)

A

Metals have lower ionization energies than non-metals, they tend to form positive ions (Cations)

55
Q

Where does IE increase on the periodic table?

A

Ionisation energy also increases as you go up the groups and across the periods. For example Hydrogen has a higher IE than Lithium, and lithium has a higher IE than Sodium. And Helium has the highest IE of all.