Periodic Trends Flashcards

1
Q

Does the atomic radius increase or decrease going across a period.

A

Decrease

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2
Q

What happens to nuclear charge going across a period.

A

The number of protons and electrons increase. As opposites attract there is a stronger electrostatic attraction between the protons and electrons.

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3
Q

Why is electron-electron repulsion across a period not a determining factor for atomic radius.

A

The attraction between protons and electrons outweigh.

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4
Q

Does the atomic radius increase or decrease going down a group.

A

It increases

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5
Q

What happens to the nuclear charge going down a group.

A

Electron numbers increase, therefore, more shells are needed. This creates more distance between the valence electrons and the atoms nucleus.

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6
Q

Why does shielding increase going down a group.

A

Shielding increases as electron numbers increase down a group.

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7
Q

What is shielding

A

Shielding is when inner electrons slightly block the valence electrons from being attracted to the atoms nucleus. This allows the valence electrons to stray away, therefore, increasing atomic radius.

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8
Q

Do cations have a smaller or larger radius than their originating atom.

A

Smaller

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9
Q

Why do Cations have a different radius compared to the atom that they originate from.

A

When the atom forms its cation its number of electrons decrease. The number of protons it hold does not change therefore the protons are pulling with the same strength on less electrons decreasing its atomic radius.

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10
Q

Do anions have a smaller or larger radius than their originating atom

A

Larger

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11
Q

Which of the 4 factors that determine atomic radius change when an atom forms its anion.

A

The number of electrons in the valence shell.

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12
Q

What is the definition of Ionisation energy

A

The amount of energy required to remove one mole of electrons from one mole of atoms in their gaseous state

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13
Q

What is the purpose of Ionisation energy of atoms in their gaseous state.

A

If Ionisation energy was calculated from an atom in its liquid or solid state the calculation would be incorrect and you would be calculating the energy used to break down the intermolecular forces also.

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14
Q

What is the definition of electronegativity

A

The tendency of an atom to attract bonding electrons in a covalent bond. (How desirable electrons are to its atom)

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15
Q

What is the electronegativity trend across a period and why.

A

Electronegativity increases across a period as electrons are held more tightly to its protons due to the rule of attraction.

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16
Q

What is the electronegativity trend down a group on the periodic table.

A

Electronegativity decreases as electrons are further away from their nucleus due to shielding.

17
Q

What is the Ionisation trend across a period?

A

Ionisation energy should increase as the atomic radii gets smaller and electrons are more attracted to its nucleus.

18
Q

What is the exceptions to ionisation trends?

A

Orbitals that are half filled or full filled will have higher Ionisation energies.

19
Q

What is the Ionisation trend down a period?

A

Ionisation energy will decrease down a period as the atomic radii gets bigger and there is less attraction between the valence electrons and their corresponding nucleus.