periodic table Flashcards
Common properties of alkali metals
- They are all reactive metals. They have to be stored under oil to stop them reacting with oxygen and water vapour in the air
- They are soft and can be cut with a knife.
- They all have low melting points and low densities compared to other metals,
- They form positive ions with +1 charge.
Reaction with water
They react spontaneously with water to produce hydrogen gas and the metal hydroxide (alkali). The reaction is exothermic.
Metal + water → metal hydroxide + hydrogen
2Li + 2H2O → 2LiOH + H2
2Na + 2H2O → 2NaOH + H2
alkali metals Reaction with non-metals
They react strongly and directly with non-metals to form salts. These salts are white, crystalline and ionic solids which dissolve in water.
General trends down the group 1
(a) decreasing melting point
(b) increasing density
(c) increasing reactivity
Explain why the reactivity of group 1 metals increases as you go down the group.
The atomic radius increases down the group (the atoms get larger).
The force of attraction between the nucleus and outer electron decreases.
The electron is lost more easily (requires less energy to remove) from atoms lower down the group.
What are the general properties of transition metals?
- Relatively high densities.
- High melting points.
- Form coloured compounds.
- Often act as catalysts.
‘Transition metals have variable
____ ____’
Oxidation states
Example of oxidation states
Example: iron atoms can lose either two electrons, to form Fe2+ ion, or three electrons, to give Fe3+.
Iron(III) oxide ,Fe2O3
Iron(II) oxide ,FeO
REACTION WITH WATER
Lithium
Sodium
Potassium
Lithium Floats and gives off hydrogen gas (effervescence)
Sodium Vigorous Reaction and moves very quickly
Potassium Explosive Reaction, lilac flame
Hallogens properties
- density and melting point increase down the group
- Poisonous
- Down the group, the colour darkens
- They produce salts called halides
Example: chlorides, bromides, iodides - Diatomic
- Reactivity decreases down the group,
(because it has to gain an electron,
so the closer the electron is to the positive nucleus, the more easily it will be gained,
so atoms with fewer shells will react more easily) - Do not conduct electricity
The colour and state of each element in group 7 at r.t.p
fluorine
chlorine
bromine
iodine
astatine
fluorine – pale yellow gas
chlorine – pale yellow-green gas
bromine – red-brown liquid
iodine – grey-black solid
astatine – black solid
What happens in a displacement reaction
A halogen displacement reaction occurs when a more reactive halogen displaces a less reactive halogen from an aqueous solution of its halide
Colour in solutions
Halide salts (e.g. KCl, KBr, KI)
Chlorine water
Bromine water
Iodine water
Halide salts (e.g. KCl, KBr, KI) are colourless
Chlorine water is colourless
Bromine water is orange
Iodine water is brown
Noble gas properties
non-metals
have very low melting and boiling points
all monoatomic
colourless gases
Density. m.p & b.p increases down the group
Why are noble gases inert?
(‘inert’ means chemically unreactive)
The atoms have a full outer shell of electrons