Part 3: Not-fully-benzenoid PAHs Flashcards

1
Q

What is the mallory reaction?

A
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2
Q

Give the Mallory mechanism

A
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3
Q

What are Phenacenes?

A
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4
Q

Draw [3]Phenacene

A

Phenanthrene

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5
Q

Draw [4]Phenacene

A

chrysene

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6
Q

Draw [5]Phenacene

A

picene

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7
Q

[6]phenacene

A

fulminene

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8
Q

Wittig reaction!

A
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9
Q

Mallory reaction towards higher Phenacenes

A
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10
Q

Sommelet reaction!

A
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11
Q

How can you combine Sommelet reaction and Wittig to produce phenacenes?

A
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12
Q

Another synthetic method towards higher phenacenes

A
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13
Q

what is contorted hexabenzocoronene (c-HBC)

A
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14
Q

Corey-Fuchs reaction!

A
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15
Q

Katz-modified Mallory reaction!

A
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16
Q

Barton-Kellogg reaction!

A
17
Q

Give the mechanism of the Barton-kellog reaction!

A
18
Q

Synthesis of Triphenylene Derivatives

A
19
Q

Intramolecular Photochemical Cyclodehydrohalogenation Reaction

A
20
Q

Intramolecular Photochemical Cyclodefluorination Reaction

A
21
Q

Intramolecular Aryl-Aryl coupling through C-F bond activation

A