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PAHs > first presentation > Flashcards

first presentation Flashcards

1
Q

How does the solvatofluorochromism work?

A

These phenomena are consistent with a radiative deactivation from locally excited states in nonpolar solvents, and an emission from a low-lying charge-transfer state by intramolecular
charge transfer (ICT) in polar solvents

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2
Q

How do you call this?

A

2-(2-bromophenyl)-1,3-dioxolane

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3
Q
A

1,4-dichloroanthraquinone

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4
Q

NaPO2H2

A

Sodium hypophosphite

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5
Q

TfOH

A

triflic acid

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6
Q

KOAc

A

potassium acetate

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7
Q

Explain 8 inversion!

A
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8
Q

What is NICS(1)zz?

A

Nucleus independent chemical shift

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9
Q

What is 3D ICSS?

A

3D isochemical shielding surface

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10
Q

What is Fc/Fc+

A

Ferrocene/Ferrocenium

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11
Q

What is DBU?

A

1,8-Diazabicyclo[5.4.0]undec-7-ene
used for separation of fullerenes

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12
Q

What is CH3NO2?

A

Nitromethane
solvent and can stabilize chloride molecules

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13
Q

What is DDQ?

A

2,3-Dichloro-5,6-dicyano-1,4-benzoquinone

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14
Q

DMAC

A

Dimethylacetamide (solvent)

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PAHs (6 decks)

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