Paper 2 Topics Flashcards
What is 1 mole?
A collection of 6.02×1023 molecules
(Avogadro’s constant)
What is the molar mass of a substance?
The mass of each mole (every 6.02×1023 molecules)
Eg for He each mole has a mass of 4g
How do you calculate the molar mass of a compound eg NO2
Add up the nucleon numbers
(14+16+16=46gmol-1)
How do you calculate the number of molecules in a substance?
N = n × NA
(Number of molecules = moles × Avogadro’s constant)
What is the molecular mass and how is it calculated?
The mass of each molecule of the substance
m = M/N
(molecular mass = total mass / number of molecules)
How is the total mass of a substance calculated?
M = n × mr
(Total mass = moles × molar mass)
How do you convert a temperature from °C to K?
T(K) = T(°C) + 273
Define absolute zero
The point at which an ideal gas exerts no pressure
(0K, -273°C, molecules have no kinetic energy)
What is Boyle’s Law?
The pressure in a gas is inversely proportional to the volume it occupies
at a fixed temperature
and a fixed mass of gas
(P ∝ 1/V)
What does the P-V graph look like for an ideal gas?
How do you prove Boyle’s law graphically?
Plot a graph of P against 1/V
Should be a straight line passing through the origin
What is Charles’ Law?
Volume a gas occupies is directly proportional to the temperature of the gas
at a fixed pressure
and a fixed mass of gas
(V ∝ T)
How do you prove Charles’ law by graph?
Plot a graph of V against T
Should be a straight line passing through the origin
For an ideal gas, what does a graph of V against T(°C) look like?
Note: x-intercept represents absolute zero
What is the Pressure law?
The pressure of a gas is directly proportional to the temperature of the gas
at a fixed volume
and a fixed mass of gas
How do you prove the pressure law graphically?
Plot a graph of P against T
Should be a straight line passing through the origin
For an ideal gas, what does a graph of P against T(°C) look like?
Note: x-intercept is absolute zero
What is the ideal gas relationship?
When can you use the ideal gas relationship?
If the mass of the gas is constant
How do you calculate the work done compressing or expanding a gas?
Calculate the area under the curve
What is the general equation for pressure?
P = F / A
(Pressure = Force / Area)
How does a gas exert a pressure on a container?
- The gas molecules collide with the container walls changing their momentum.
- This creates a force on the molecule and the wall
- Exerting a pressure
What are the 5 conditions for an ideal gas?
- Volume of the molecules must be much smaller than the volume of the gas itself
- The intermolecular forces are negligible
- The collision time of molecules with each other and the walls is much less than the time between them
- The collisions are elastic (no loss in KE)
- The molecules’ motion is random
How does Brownian motion explain the random motion of smoke?
- Air molecules are moving randomly
- They collide with the smoke changing momentum and exerting a force on the smoke particles
- If at one moment there are more collisions on one side than the other
- The smoke particle has a resultant force so accelerates in that direction
Explain Boyle’s Law using the molecular Kinetic Theory
- When volume of container is decreased
- More collisions per second
- So total momentum change bigger (▲p)
- So force exerted bigger
- So pressure bigger (From P = F/A)
Explain Charles’ Law using the molecular kinetic theory
- When temperature is increased
- Volume increases to increase the distance travelled between collisions
- Molecules have greater kinetic energy but travel further so frequency stays same
- Change in momentum (▲p) stays constant
- So pressure is constant (P = F/A)
Explain the Pressure law using the molecular kinetic theory
- As temperature increases
- The average kinetic energy of the molecules increases
- Increasing the number of collisions per second with container walls
- So greater change in momentum
- Greater force and pressure exerted (P = F/A)
How would you use this equation to work out the density of a gas?
How do you calculate crms from a list of speeds?
- Square the speeds and add up
- Take a mean of the squares
- Square root the value
How is cms calculated?
cms = (crms)2
What are the units of cms?
[m2s-2]
What does the maxwell-boltzmann distribution tell us about gases?
Molecules have a range of kinetic energies.
So temperature of the gas is a measure of the average kinetic energy.
For these equations how do you calculate the internal energy of the gas?
Multiply each by the number of molecules of the gas.
How do two objects brought into contact reach thermal equilibrium?
- There is a net flow of thermal energy from the hotter object to the colder object
- Until both objects are at the same temperature
- And there is now no net flow of thermal energy
Define specific heat capacity
The energy required to increase 1kg of a substance by 1K [Jkg-1K-1]
When would you use this equation?
To calculate the mass flowing per kg of a fluid
Why does the temperature of a substance changing state not increase?
The thermal energy is used to break some of the intermolecular bonds (solid → liquid) or the rest of the intermolecular bonds (liquid → gas)
Define specific latent heat of fusion
The energy required to change the state of 1kg of a solid to a liquid at its melting point.
Define specific latent heat of vaporization
The energy required to change the state of 1kg of a liquid to a gas at its boiling point.
What is wrong with this?
Haven’t considered the change of states. Need to break it into 3 equations:
How are these two gravitational fields similar? How are they different?
Both are uniform (constant field strength)
Closer field lines represent stronger field
How are radial and uniform fields different?
Radial fields have a decreasing field strength
(Field lines increasing in separation)
Uniform fields have a constant field strength
(Field lines constant\ separation)
In gravitational fields when can you use the equation EP = mgh?
Over small distances
When radial fields are approximately uniform
And g is approximately constant
Why can’t SUVATs be used for radial gravitational fields?
SUVATs need a constant acceleration
Radial fields have a variable field strength and so a variable acceleration
What are equipotentials and how are they related to field lines?
An equipotential has the same potential along that line
(So no work is done moving along the equipotential)
They are always perpendicular to field lines
What is Newton’s Universal Law of Gravitation?
Force acting between two bodies is:
- Directly proportional to the product of their masses (F∝m1m2)
- Inversely proportional to the square of their separation (F∝1/r2)
Define gravitational field strength and state its units
The force acting per unit mass on an object in a gravitational field
[NKg-1] or [ms-2]
In the gravitational field strength equation what does M represent?
The mass of the object creating the field
If the Earth is exerting a force on the rocket of 5000N,
What force is the rocket exerting on the Earth?
5000N also. An equal and opposite force from Newton’s 3rd Law
(Which has little effect on the Earth because it has so much more mass)
How do you calculate the resultant gravitational field strength at a point between two bodies?
- Calculate the field strength for each body in turn (ignoring the other one)
- Calculate the difference between the field strengths (g is a vector)
How do you you calculate the field strength (or force) neutral point between two bodies in a gravitational field?
What is the definition of and the equation for absolute potential energy in a gravitational field?
The work done moving an object from infinity to that point in the field
Why is gravitational potential energy always negative?
- Gravitational potential energy is 0 at infinite distance
- And decreases inwards as you move towards object creating field
- (So must go negative)
What is gravitational potential?
The work done per unit mass moving an object from infinity to that point in a field
In this equation for gravitational potential what object is represented by mass M?
The mass of the object creating the field
Which astronaut has a greater loss in gravitational potential energy?
Neither. Potential energy (and potential) are scalar quantities so are unaffected by the path
Both decrease by 1440MJ
What is the mistake here?
In the second stage the mass of the satellite must be used
(Not the Earth’s mass again)
If a gravitational fields question uses the word ‘height’ what must you do?
Height is the distance above the surface
So you must add on the radius of the planet/star/object
Why can’t two objects have a neutral point for gravitational potential? (or GPE)
Gravitational potential from both is negative
So they combine
To increase the magnitude of the potential
When can you use these proportionality equations in Gravitational fields?
When the mass or masses are constant
In gravitational fields What does a force-separation graph look like?
And what else does the graph tell you?
The area under the curve is the change in potential energy moving between the two separations
In gravitational fields What does a field strength-separation graph look like?
And what else does the graph tell you?
The area under the curve is the change in potential moving between the two separations
In gravitational fields What does a potential energy-separation graph look like?
And what else does the graph tell you?
The gradient of a tangent is the magnitude of the force at that point
In gravitational fields What does a potential-separation graph look like?
And what else does the graph tell you?
The gradient of a tangent is the field strength at that point
What is the equation for gravitational field strength within a planet?
(r ≤ R)
This part of the graph is linear as g ∝ r
How do you derive the equation for gravitational field strength inside a planet?
- Use general equation for density (M/V)
- With V as the volume of a sphere (4/3πr3)
- Sub into general equation for field strength
How do you derive Kepler’s 3rd Law? (r3 ∝ T2)
- Equate centripetal force to force due to gravity
- Substitute in angular speed formula (from circular motion)
- Rearrange
How do you derive the formula for the velocity of a satellite orbiting a planet or star?
- Equate centripetal force to force due to gravity
- Rearrange
Which planet has the greatest orbital velocity and why?
Mercury
It is closest to Sun so smallest r
How do you derive the formula for the escape velocity of a planet or star?
In these 3 equations what does the mass refer to?
The mass of the object creating the field
Why does a satellite not need to be above the escape velocity to reach low Earth orbit?
- Escape velocity only applies to objects without engines (that can’t increase their KE)
- Satellite isn’t escaping the field (so doesn’t need as much KE)
How do you calculate the Kinetic Energy of a satellite orbiting a planet?
Substitute orbital velocity into equation for kinetic energy
How do you calculate the total energy of an orbiting satellite?
Add the kinetic and potential energy together…
What is the difference between a geosynchronous and geostationary orbit?
Both have orbital periods of 24 hours (the same as the Earth)
How are geostationary and polar satellites different?
Geostationary satellites orbit above the same point of the equator and have an orbital period of 24 hours
Polar satellites orbit over the North and South pole with an orbital period of much less (around 2 hours)
What are polar satellites used for?
- Communication for high latitude regions (close to the poles)
- Espionage (spying)
- Meteorology (weather)
What are Geostationary satellites used for?
- Satellite television
- Mobile Phone Communications
- GPS
What 4 things do magnetic fields affect?
- Charges moving in the field
- Conductors with a current passing through
- Other magnets
- Magnetic materials
What do the field lines for a bar magnet look like?
Field lines always act North → South
What do the field lines look like between two opposite poles?
Field is uniform between the poles
What do the field lines look like between two like poles?
How are field lines represented ‘going into the page’?
How are field lines represented ‘coming out of the page’?
This conductor in a magnetic field has a current passing through
But doesn’t experience a force
Why?
Because it is parallel to the field lines
When do you use Fleming’s Left hand Rule?
- Looking at DC motors
- Looking at charges moving in a magnetic field
How do you calculate the force on a conductor placed at an angle in a magnetic field?
First use trigonometry to calculate the perpendicular component of its length
Why does the reading on the balance increase when a current runs through the conductor?
The magnetic field pushes up on the conductor
So the conductor pushes the magnets down (Newton’s 3rd Law)
How can you increase the mechanical energy produced by the DC motor?
Increase the torque by:
What do the commutator rings do in the DC motor?
Switch connections of the bars every 180°
So direct current is produced
What happens if the commutators are removed from the DC motor?
Force on each bar won’t change
So coil will reach equilibrium in vertical position
And won’t continue spinning
Why does an electron move in a circular path in a magnetic field?
Force from magnetic field perpendicular to velocity of electron
How do you apply Flemming’s left hand rule to a negative charge moving in a field?
Current acts opposite to the velocity
How do you apply Flemming’s left hand rule to a positive charge moving in a field?
Current acts in the same direction as the velocity
When should you use each equation?
F=BIL on a conductor in a magnetic field (with current)
F=BQv on a charge in a magnetic field (moving)
How do you calculate the radius of the orbit of a charge moving in a magnetic field?
Equate the magnetic and centripetal forces
How do you explain the different curvatures of radiation () passing through a magnetic field?
Greater the specific charge → Smaller r (Bigger deflection)
How do you calculate the speed of a charged particle accelerated through an electric field?
How much work does a magnetic field do on a moving charge?
0J because the force and velocity vectors are perpendicular
So the charge does not increase its kinetic energy
In a mass spectrometer how does the velocity selector work?
Unless an ion’s velocity = E/B, it will travel in a parabola and miss the gap
In a mass spectrometer how does the mass separation work?
The ions have the same velocity (from the velocity selector)
So deflect by specific charge
In a particle accelerator why are both magnetic and electric fields needed?
In the cyclotron what is the purpose of the alternating current and magnetic field?
Alternating current → Electric Field between ‘Dees’ → Increases kinetic energy
Magneti Field → Moves particle in circular path in ‘Dees’ → Containing particle
In the cyclotron why is the frequency of the alternating current constant?
As the charge speeds up → Travels further in each Dee → So takes same time
How do you calculate the AC frequency of the cyclotron?
Note: f is independent of v
So the frequency is constant
How do charges interact in these situations?
- Like charges repel
- Opposite charges attract
Which direction will these charges move?
Electric field lines shows direction of Force on +ve charges
(-ve charges are opposite)
How are radial and uniform electric fields different?
- Radial fields have a varying field strength (weaker when further apart)
- Uniform fields have a constant field strength
For electric fields, how are are equipotentials related to the field lines?
Equipotentials always perpendicular to field lines
How can you change this situation to increase the force on the charge?
- Increase field strength
- Increase magnitude of charge
What field lines are produced by…
a) +ve charge
b) -ve charge
Field lines always act…
- Away from +ve
- Towards -ve
How do the field lines look for these two interacting oppositely charged particles?
How do the field lines look for these two interacting like charged particles?
NOTE: Field lines never cross