Paper 1 inorganic chemistry Flashcards
word equation for reaction between alkali metals and water
alkali metal + water = metal hydroxide + hydrogen
What is the solution of the reaction of an alkali metal with water
alkaline
trend in reactivity of alkali metals
more reactive down the group
product of lithium and air reaction
lithium oxide
product of sodium with air
mixture of sodium oxide and sodium peroxide
potassium and air product
potassium peroxide and potassium superoxide
what suggests they are all part of the same family based on their reactions with water
produce an alkaline solution, and hydrogen, as well as a metal hydroxide
why do alkali metals react similarly
all have one electron on the outer shell
trend in melting and boiling point down group 1
boiling and melting point decreases down the group and the relative atomic mass increases
why does boiling point decrease down group 1
more shells of electrons so weaker electrostatic attraction
trend of colour and atomic mass in halogens
colour gets darker at you go down the group and mass increases
trend of boiling point in halogens
boiling point increases down the group
state and colour of chlorine at rtp
green gas
state and colour of bromine at rtp
red-brown liquid
state and colour of iodine at rtp
dark grey crystalline solid
colour of bromine gas
orange
colour of iodine gas
purple
trend in reactivity of halogens
less reactive as you go down the group
what experiments prove that reactivity decreases down the group
reactions with hydrogen - fluorine reacts violently, chlorine reacts violently only when exposed to light, bromine only reacts when with a burning splint
word equation for halogen plus hydrogen reaction
hydrogen + halogen = hydrogen halide
which side of arrow are electrons in ionic half equation in reduction
left
which side of arrow are electrons in ionic half equation in oxidation
right
what happens to whatever gets displaced in halogen displacement
oxidation
what happens to whatever displaces the other one in halogen reactions
reduction
therefore what is trend in terms of oxidation and reduction with halogens
more reactive = reduced
what is the oxidising agent
whatever is being reduced
what is the reducing agent
whatever is being oxidised
colour of iodine solution
dark brown
colour of bromine solution
orange
colour of chlorine solution
pale green
the colour of a solution after displacement reaction corresponds to the colour of what
the colour of solution of what has been displaced
composition of air approximate percentages
nitrogen = 78
oxygen = 21
argon = 0.9
carbon dioxide = 0.04
describe reaction of magnesium and oxygen
burns with bright white flame
produces white powder
alkaline when dissolved in water
describe the reaction of hydrogen with oxygen
explosive
orange/yellow flame
produces only water
describe the reaction of sulphur and oxygen
pale blue flame
produces sulphur dioxide
acidic when dissolves in water
general word equation for thermal decomposition of metal carbonates
metal carbonate = metal oxide + carbon dioxide
metal and acid reaction equation
metal + acid = salt + hydrogen (MASH)
metal and water reaction
metal + water = metal hydroxide + hydrogen
what do you use instead of water when dealing with a less reactive metal and which metals
steam
magnesium, zinc, iron
which metal wont react with water or steam
copper
what type of salt is produced from hydrochloric acid
chloride salts
what type of salt is produced from sulphuric acid
sulphate salts
reactivity series
Potassium Sodium Lithium Calcium Magnesium Aluminium Carbon Zinc Iron Tin Lead Hydrogen Copper Silver Gold
what things must be present for rusting to occur
oxygen and water
what type of reaction is rusting
corrosion
chemical equation for rusting
iron + oxygen (+water) = hydrated iron (III) oxide
which are the only two things that rust
iron and steel (because it is an alloy of iron)
suggest some barrier methods of rust prevention
painting, oiling (lubricating), greasing, coating with plastic or a less reactive metal to prevent oxygen entering
what is the sacrificial method of protection from rust
adding blocks of zinc or magnesium to surface, which will react with oxygen
what is the method of galvanising
coating in zinc layer
what colour is methyl orange in acid/alkali
red/orange in acid, yellow in alkali
what colour is phenolphthalein in acid/alkali
colourless in acid, pink/red in alkali
metal oxide and acid reaction equation
metal oxide + acid = salt + water
metal hydroxide and acid reaction equation
metal hydroxide + acid = salt + water
acid and ammonia reaction equation
acid + ammonia = ammonium salt
difference between ammonia and ammonium
ammonium is NH4+ and ammonia is NH3+ and ammonia is usually a gas
acid and base reaction equation
acid + base = salt + water
acid and metal reaction equation
acid + metal = salt + hydrogen
acid and metal carbonate reaction equation
acid + metal carbonate = salt + water + carbon dioxide
acid definition
a substance containing H+ hydrogen ions which donate protons and have a pH less than 7
base definition
a substance containing OH- hydroxide ions and are proton acceptors (receive protons), pH greater than 7
difference between base and alkali
alkalis are soluble bases
Equation for metal and steam reaction
Metal + steam = metal oxide + hydrogen