Package 2 Flashcards
Lattice enthalpy
The heat that is absorbed when 1 mole of solid ionic compound is broken up to form gaseous ions under standard conditions
Lattice enthalpy depends on what factors
- The electrostatic forces between two oppositely charged ions
- The distance between ions
What happens to the lattice enthalpy when the ionic charge increases
The ionic attraction increases and increases the lattice energy
Lattice energy vs boiling/melting point
Proportional
Volatility in ionic compounds
Very low because the electrostatic forces of attraction are very strong
Solubility of ionic compounds in water
Since water has a negative and positive end, it attracts the negative and positive ions of a compound and are hydrated
Solubility of ionic compounds in non polar things
Insoluble because there is no attraction between the liquid and the ions
CaCO3 in water
Only a small amount dissolves
Conducting electricity
Only possible in molten or dissolved in water
Why are ionic compounds brittle
When force is applied the same charge ions line up and therefore cause repulsion forces, splitting apart
Chlorides of later elements (Al, Si, P and S)
Molecular covalent and have very low melting points and do not conduct electricity
Electronegativity
Amount of attraction that an atom has for the shared pair in a covalent bond
Xp for each bond
Ionic: Xp is greater than 1.8
Polar covalent: 0 < Xp < 1.8
Pure covalent: 0
Sharing of electrons in each bond
Ionic: Complete transfer
Polar: Uneven sharing
Pure: Equal sharing