P4 - Atomic Structure Flashcards

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1
Q

Who replaced the plum pudding model with the nuclear model?

A

Rutherford

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2
Q

When is the earliest known thought about atoms?

A

Democritus in 5th Century BC Greece thought all matter was made of identical lumps called atomos

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3
Q

Who discovered, (and rearrange them in chronological order):

a) Protons
b) Neutrons
c) Electrons

A

c) J J Thompson, round 1900
b) Rutherford
a) James Chadwick

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4
Q

What was John Dalton’s theory about atoms? 1804

A

He agreed with the Greek Democritus that matter was made of tiny spheres (atoms) that couldn’t be broken up, but he thought each element was made up of a different type of atom

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5
Q

What were J J Thompson’s conclusion about atoms? Early 1900’s

A

He discovered particles called electrons that could be removed from atoms, so Dalton wasn’t quite right. Thompson suggested atoms were spheres of positive charge with tiny negative electrons stuck in them like fruit in a plum pudding - this is the plum pudding model

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6
Q

What was Rutherford’s experiment? 1909

A

Scientists tried firing alpha particles at thin gold foil, expecting them to pass straight through the gold sheet, or only get slightly deflected.
However, most did go straight through, but others were deflected in all sorts of directions. The plum pudding model couldn’t explain this.

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7
Q

After Rutherford’s experiment, what did he conclude? 1909

A

Because alpha particles were deflected back, they realised that most of the mass of the atom must be concentrated at the centre, in a tiny nucleus. It must also be positively charged, as it repelled the positive alpha particles.
They also realised - as most alpha particles passed through fine - that most of the atom is empty space.
He concluded an early version of the nuclear model of the atom, where there was a TINY positive ball of charge at the centre, then a cloud of electrons around it

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8
Q

What did Niels Bohr discover and how did he develop the atomic model?

A

He discovered that electrons all orbited at certain distances from the nucleus called energy levels (or shells)

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9
Q

How did James Chadwick develop the atomic model? 1932

A

He proved the existence of the neutron, explaining the imbalance between the atomic and mass numbers.
This led to the current model of the atom, with electrons orbiting in shells, then protons and neutrons in the tiny nucleus at the centre

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10
Q

Complete the sentence:

The number of protons =

A

The number of electrons. (as protons and electrons have an equal but opposite charge, and atoms have no overall charge, so they must cancel out)

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11
Q

How many times smaller in the radius of the nucleus compared to the rest of the atom?

A

10,000

In case I phrased it wrong, “The nucleus… its radius is abut 10,000 times smaller than the radius of the atom)

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12
Q

What is the radius of an atom roughly?

A

1 x 10^-10 (to the power of -10)

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13
Q

Fill the blanks:
Electrons in energy levels can ____ within (or sometimes _____) the atom. If they gain energy by absorbing __ _________, they move to a ______ energy level, further from the nucleus. If they release this same type of energy, they move to a _____ energy level, ______ to the nucleus. If one or more outer electrons leave the atom, the atom becomes a __________ _______ ___

A
Move
Leave
EM radiation (electromagnetic I think)
Higher
Lower
Closer
Positively charged ion
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14
Q

What are isotopes?

A

Isotopes are different forms of the same element.
OR they are atoms with the same number of protons (the atomic number is the same, so the same charge is on the nucleus), but a different number of neutrons (a different mass number)

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15
Q

What subatomic particle defines the element?

A

Protons - the atomic number

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16
Q

What subatomic particle determines if it is an isotope?

A

Neutrons - the mass number

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17
Q

All elements have different isotopes, but none of them are stable. True or false?

A

False - normally only one or two stable ones

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18
Q

What is the mass number?

A

The sum of protons and neutrons, as they are they only too that have a clear mass of 1 (electrons are relative to 0)

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19
Q

What do unstable isotopes tend to do?

A

Decay into other elements and give out radiation as they try and be more stable.
They try and balance the number of protons and neutrons in the nucleus or get rid of excess energy.
This process is radioactive decay

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20
Q

What is radioactive decay?

A

The process of an unstable isotope decaying into other elements and give out radiation as they try and become more stable.
They try and balance the number of protons and neutrons in the nucleus or get rid of excess energy.

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21
Q

What do radioactive substances release?

A

Ionising radiation - alpha, beta or gamma (and more that we don’t need to know)
They can also release neutrons when they decay ro rebalance the number of protons and neutrons

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22
Q

What is ionising radiation?

A

The type that knocks electrons off other atoms, creating positive ions

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23
Q

What determines how easily ionising radiation will be able to knock off the electrons from ther atoms?

A

Its ionising power

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24
Q

What are these radiation types?

a) β
b) γ
c) α

A

a) Beta radiation
b) Gamma radiation
c) Alpha radiation

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25
Q

Give a use for each ionising radiation

A

Alpha particles - used in smoke detectors (it ionises air particles, causing a current to flow. If smoke is in the air, it binds to the ions - meaning the current stop and the alarm sounds)
Beta particles - Tests the thickness of sheets of metal & paper (as the particles aren’t immediately absorbed by the material like alpha radiation is, and don’t penetrate as far as gamma rays)
Gamma rays - As a medical tracer (a gamma-emitting source is injected into the patients body, and its progess is followed)

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26
Q

What are some properties of alpha radiation particles?

A

2 protons and 2 neutrons are emitted from the nucleus (like a helium nucleus)
They don’t penetrate very far into materials and are stopped quickly
They travel a few centimetres in air, and are absorbed by a piece of paper
They are strongly ionising due to their size

27
Q

What are some properties of beta particles?

A

1 electron - very fast- is emitted from the nucleus
They penetrate moderately far into materials before colliding
They travel a few metres in air and they are absorbed by a sheet of aluminium
They are moderately ionising

28
Q

What are some properties of gamma rays?

A

A wave of electromagnetic radiation released by the nucleus
The penetrate very far into materials without being stopped
They can travel very far in air and they are absorbed by thick sheets of lead or metres of concrete
They aren’t very ionising as they tend to pass through rather than collide with atoms. Eventually they hit something and do damage

29
Q

Which of the ionising radiation types are the most:

a) ionising?
b) heavy?
c) penetrating?

A

a) Alpha particles
b) Alpha particles - beta particles have basically no mass and gamma rays are waves, so have no mass
c) Gamma rays

30
Q

Uranium-238 gets radioactively decayed to become Thorium-234. What radioactive particle was released?

A

An alpha particle, as the mass number (sum of neutrons & protons) decreased by 4, which is the mass number of an alpha particle.
238 _234 .4
U —>Th + He
92 __90 . 2

ALTHOUGH gamma rays may have also been produced, as that would not affect the equation

31
Q

Give the structure of how the nuclear equation is written

A

Atom before decay —> atom after decay + radiation emitted

THE TOTAL MASS AND THE ATOMIC NUMBERS MUST BE EQUAL ON BOTH SIDES

32
Q

What does beta decay do? How/ Why?

A

It increases the charge of the nucleus.
When beta decay occurs, a neutron in the nucleus turns into a proton and releases an electron/ beta particle.
The number of protons in the nucleus has increased by 1. This increases the positive charge f the nucleus (atomic number)
Because the nucleus has lost a neutron and gained a proton during beta decay, the mass of the nucleus doesn’t change (protons and neutrons have the same mass)

33
Q

What happens in beta decay?

A

A neutron in the nucleus turns into a proton and releases an electron/ beta particle
The number of protons in the nucleus has increased by 1. This increases the positive charge f the nucleus (atomic number)
Because the nucleus has lost a neutron and gained a proton during beta decay, the mass of the nucleus doesn’t change (protons and neutrons have the same mass)

34
Q

How do you write these in nuclear equations:

a) Alpha particle
b) Beta partcle

A

a) As a helium particle (He, 4 top, 2 bottom)
b) 0e
- 1

35
Q

What does alpha decay do to the nucleus?

A

It decreases its mass and charge, as 2 protons and 2 neutrons have gone, so +2 has gone, and 4 mass has gone

36
Q

Will a new element from in alpha and beta emissions?

A

Yes, as the proton number changes in both of them

37
Q

Carbon-14 undergoes beta-decay to form nitrogen-14. Write the nuclear equation

A

14 ___14 . 0
C —> N + e
6 ___ 7 .-1

38
Q

Carbon-14 radioactively decays into Nitrogen-14. What type of radiation has occurred?

A

Beta radiation, as that does not affect the mass number, as the sum of neutrons and protons remains the same.
HOWEVER, gamma radiation could have occured as that would not affect the atomic or mass number

39
Q

Why would a nucleus emit gamma rays?

A

To get rid off excess energy

40
Q

The radioactivity of a source decreases over time. True or false?

A

True, each time a radioactive nucleus decays to become a stable nucleus, the activity as a whole will decrease (older sources emit less radiation)

41
Q

Radiation is a…

A

Completely random and spontaneous process

42
Q

How can you measure radiation?

A

With a Geiger-Muller tube and counter, which records the count-rate (the number of radiation counts reaching it per second)

43
Q

Radioactive decay is completely random. What does this mean?

A

You can’t predict exactly which nucleus in a sample will decay next, or when any one of them will decay

44
Q

What is half-life?

A

The time it takes for the amount of radiation emitted by a source to halve
The half-life is the time taken for the number of radioactive nuclei in an isotope to halve”
The time taken for the activity (and so count-rate) to fall to half of its original value

45
Q

What can half-life be used to find?

A

The rate at which the source decays - its activity

46
Q

What does “activity” mean? What is its units?

A

The rate of which a source decays.
Measured in becquerels (Bq)
1 Bq is 1 decay per second

47
Q

What is the problem with trying to measure how long it will take all the unstable nuclei of an isotope to decay?

A

The activity never reaches 0, which is why half-life is used to see how quickly the activity drops

48
Q

Give the fancy definition for half-life

A

“The half-life is the time taken for the number of radioactive nuclei in an isotope to halve”

49
Q

The initial activity of a sample is 640 Bq. Calculate the final activity as a percentage of the intial activity after 2 half-lives

A

1) Find the activity of each half-life:
1 half-life - 640/2 = 320
2 half-lives 320/2 = 160

2) Now divide the final activity by the initial activity, then x100 to make a percentage
(160/640) x 100 = 25%

50
Q

On a half-life graph, what are the axis?

How do you find the half-life from this?

A

Activity in becquerels (y-axis)
against time in seconds (x-axis)

y finding the time interval on the bottom axis corresponding to a halving of the activity on the vertical axis. DO ACTIVITY HALVED FIRST

51
Q

What is the risk with using radiation?

A

Ionising radiation can enter living cells and ionise atoms within them. This can damage the cells (which can cause cancer for example) or kill them off completely.

52
Q

What is irradiation?

A

Exposure to radiation

53
Q

What is contamination?

A

Radioactive particles getting onto objects

54
Q

What is the difference between irradiation and contamination?

A

Irradiation is exposure to radiation
Contamination is radioactive particles getting onto objects
Irradiating something doesn’t make it radioactive, but contamination means the radioactive particles can decay, releasing radiation near you, so can cause harm

55
Q

How can you reduce the effects of irradiation?

A

Keeping sources in lead lined boxes, standing behind barriers, sometimes being in a different room and remote controlled arms

56
Q

Give an example of contamination, and why it’s dangerous

A

If you touch a radioactive source without gloves, your hand is contaminated.
These contaminating atoms may then decay, releasing radioactive particles which can cause harm, especially if they get inside your body
Gloves and tongs should be used when handling sources to avoid particles getting stuck to your skin or under your nails

57
Q

What do some industries do to protect themselves from breathing in radioactive particles?

A

They wear protective suits

58
Q

What does the seriousness of irradiation and contamination depend on?

A

The source

59
Q

Outside of the body, which type(s) of radiation is/are the most dangerous?

A

Beta and gamma sources, because they can penetrate the body and get to delicate organs. Alpha is less dangerous as it can’t penetrate the skin and is easily blocked by a small air gap

60
Q

High levels of irradiation from all sources are dangerous, but especially from ones that emit what?

A

Beta and gamma radiation

61
Q

Inside of the body, which type(s) of radiation is/are the most dangerous?

A

Alpha radiation, because they do all the damage in a very localised area. So contamination, rather than irradiation is the biggest concern with alpha sources

62
Q

Why is beta radiation less damaging inside the body?

A

Because the radiation is absorbed over a wider area, and some passes out of the body altogether.

63
Q

Why are gamma sources the least dangerous inside the body?

A

As they mostly pass straight through, and they have the lowest ionising power

64
Q

Which types of radiation are the most dangerous with:

a) Irradiation
b) Contamination

A

a) Beta and Gamma, because they can travel further then penetrate the body
b) Alpha, because the alpha particles on the object is dangerous, as it acts in a very localised area and can’t travel far