P1-Topic 4- Chemical Changes 2022 Flashcards

1
Q

What is oxidation?

A

Oxidation - When a substance gains oxygen

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is reduction?

A

Reduction - When a substance loses oxygen

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

what is a metal and oxygen reaction? 2

A

Metals + oxygen -> metal oxides

Known as oxidation reactions because the metals gain oxygen

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What is the reactivity series of metals?

A

The series shows the metals in order of their reactivity

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What are the trends in

reactivities of metals in reactions with acids/water? 4

A

Metals above H₂ in reactivity series react with acid to produce H₂

The more reactive the metal is, the quicker and more violent reaction with acid occurs

Metals below H₂ don’t react with acids.

Not all metals above H₂
react with water - mostly Group I and II metals.

Aluminium
is the borderline case

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What is a displacement reaction?

A

A reaction where a more reactive metal displaces a less reactive metal from a
compound

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what is the reactiviy of a metal related to.

A

The reactivity of a metal is related to its tendency to

form positive ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

how does a metal (K,Na,Li,Ca) react with water 2

A

higher the reactivity K,Na the react violently, very quik

Ca is more slow

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

how does a metal (Ca,Mg,Zn,Fe,Cu) react with an acid

A

the higher the reactivity the more quick the reaction is

Ca-very quick
Mg quick

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

How are unreactive metals found in Earth?

A

In their natural state (well, they are unreactive…)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

How can metals less
reactive than carbon be
extracted? 4

A

by reduction with carbon

Carbon displaces the metal in a metal oxide

gets oxidised to form carbon oxides

Metal from the metal oxide gets reduced to the pure metal

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

How are metals more reactive than carbon extracted?

A

By electrolysis

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

what has been oxidised and reduced in 2Na + 2HCl -> 2NaCl + H₂?

A

sodium = 2Na -> 2Na(+) +2e-
Na has lost electrons & has been oxidised

2Cl- > 2Cl- has not been
oxidised or reduced

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

What is the general equation for a reaction between metals+ acids?

What type of reaction is this 2

A

Metal + acid → salt + hydrogen

Redox reaction, also a displacement reaction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Which metals in the reactivity series will react with acid?

A

Those above hydrogen

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

what are bases 2

A

chemical that can neutralise acids producing a salt + water

those soluble in water are called alkali’s

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

What is the general equation for the reaction between metal carbonate and acid?

A

Metal carbonate + acid → salt + water + carbon dioxide

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

What is the general equation for
the reaction between metal oxides
and acids?

A

Metal oxide + acid → a salt + water

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

What is a redox reaction?

A

A reaction where both oxidation and reduction occurs

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

How is a soluble salt formed?

A

a) React the excess acid with some insoluble chemical (e.g. metal oxide)
b) Filter off the leftovers
c) Crystallise the product

21
Q

What do acids and alkalis produce in aqueous solutions?

A

Acids produce hydrogen ions, alkalis produce hydroxide ions

22
Q

State the general equation for a neutralisation reaction in a short, ionic form. water

A

H(+) + OH(−) → H₂O

23
Q

What is the pH scale and what does a pH of 7 show?

A

The measure of acidity/alkalinity of a solution

neutral solution
7+ alkaline =purple
7- acidic= red

24
Q

What is a strong acid? 2

A

completely ionised in aqueous solution.

HCl→H+ +Cl-
hydrochloric, nitric and sulfuric acids.

25
What is a weak acid?
partially ionised in aqueous solution H₂CO₃ ⇌ H+ + HCO₃- ethanoic, citric and carbonic acids
26
What happens to pH scale as it decreases by 1 unit.
The pH decreases the hydrogen ion concentration of the solution increases by a factor of 10 (1 order of magnitude).
27
What is a concentrated acid ? What is a dilute acid?
the amount of acid molecules in a given volume of solution Concentrated acid has more moles of acid per unit volume than dilute (dilute refers to solutions of low concentrations)
28
Is this the same as a strong and weak acid?
It is not the same concentration is not the same thing as strength of an acid. ``` Strength refers to whether the acid is completely ionised in water (strong) or only partially (weak ```
29
how to carry out a titration 9
1. Use a pipette & place 25 cm³ sodium hydroxide solution into a conical flask 2. Add 5 drops of indicator phenolpthaleine) to the alkali in the conical flask -pink 3. Place the conical flask on a white tile to see colour change clearly 4. Fill a burette with sulfuric acid using funnel 5. Add acid to the alkali until solution neutral 6. colour change add drop by drop until neutral (swirl) -colourless 7. read volume of acid added from the burette 8. read at eyelevel with the surface of the liquid, bottom of meniscus 9. Repeat until you achieve two concordant result
30
what is 1dm³
1000cm
31
What is electrolysis? 2
passing an electric current through ionic substances that are molten or in solution to break them down into elements ions are discharged (they lose/gain electrons) at electrodes
32
What is an electrolyte?
liquid/solution which conducts electricity
33
What is a cathode What is an anode?
Cathode is the negative electrode anode is the positive electrode
34
What occurs at the cathode what occurs at the anode during electrolysis?
Reduction occurs at the cathode Oxidation occurs at the anode
35
why can molten ionic compouds be electolysed
the ions can be moved freesly and conduct electricity
36
why is the elecrode made of inert material 3
so the material doesn't react with the electrolyte -carbon replaced frequently or platinum- unreactive metal
37
In aqueous electrolysis, which element is discharged at the cathode?2
negative electrode cathode -hydrogen is produced unless the metal is less reactive than hydrogen. This is because more reactive ions want to stay within the solution.
38
Oxygen is produced | at the anode unless what? 3
positive electrode anode, OH- and halide ions (Cl-, Br-, I-) are present, then one of the halide ions will be produced. If no halide is present, oxygen is formed. This happens because in the aqueous solution water molecules break down producing H+ ions and OH- ions that are discharged
39
Describe electrolysis of copper sulfate solution 2
cathode: Cu²+ +2e- →Cu anode: 4OH- → O₂ +2H₂0 +4e-
40
describe electrolsis of sodium chloride
cathode 2H+ +2e- →H₂ anode 2Cl- → Cl₂ +2e-
41
How is aluminium manufactured?
electrolysis of aluminium oxide and cryolite.
42
Why electrolysis of aluminium expensive?
Lots of energy is needed to produce the current in electrolysis which makes this process expensive
43
why a mixture is used as the electrolyte 3
it has a very high melting point so it is mixed with cryolite to lower it it reduces the amount of energy needed and saves money
44
What are the half equations in | the extraction of aluminium?
Al³+ + 3 e− → Al (cathode) reduction 2O₂− → O₂ + 4 e− (anode) oxidation Oxygen reacts with C of the anode producing CO2
45
what is the overall equation for the electrolysis of aluminium oxide
2Al₂O₃+ 4Al + 3O₂
46
Why is cryolite used in this | process?
lowers the melting point of aluminium oxide, reducing energy costs
47
why the positive electrode anode must be continually | replaced.
the oxygen molecules produced at the anode react with the graphite (carbon) forming carbon dioxide gas
48
How is oxidation and reduction defined in terms of electron transfer
oxidation- loss of electrons | reduction- gain of electrons
49
Rules for electrolysis of ionic soloutions 4
cathode(negative)- metal produced if less reactive than hydrogen hydrogen produced if the metal is more reactive than hydrogen anode(positve)-If the negative ion is simple (eg Cl- or Br-), then that element is produced If the negative ion is a complex ion (eg NO3-, SO42-, CO32-), then oxygen is produced from the hydroxide ion present instead.