Oxidation - Reduction Reactions Flashcards
oxidation
loss of electrons
reduction
gain in electrons
Oxidising agent
accepts electrons and gets reduced
Reducing agent
donates electrons and gets oxidised
Identifying Redox Reactions
determine whether or not it is even an oxidation-reduction reaction
requires species that exhibit a change in oxidation states during the reaction
balance redox equations
elements
H2O
H+
e-
Rusting
corrosion of iron
most common corrosion of metal
oxygen and water must be present
redox reaction whereby oxygen acts as the oxidising agent and iron acts as the reducing agent
Rusting
surface of iron at the middle of the water droplet serves as the anode, the electrode at which oxidation occurs. The iron atoms here lose electrons to form iron(II) ions.
The electrons flow to the edge of the water droplet, where there is plenty of dissolved oxygen. The iron surface there serves as the cathode, the electrode at which reduction occurs.
Oxygen gains the electrons and is reduced to hydroxide ions.
The iron(II) ions produced combine with the hydroxide ions to form iron(II) hydroxide.
Rusting equations
O2 + 2H2O + 4e = 4OH-
Fe2+ 2OH- = Fe(OH)2
anode: 2Fe = 2Fe2+
cathode: O2 + 2H2O = 4OH-
overall: 2Fe + O2 + 2H2O = 2Fe(OH)2
Common oxidising agent
H2SO4
KMnO4
K2Cr2O7
MnO2
Cl2
H2O2
Common reducing agents
H2
Zn
C
CO
LiAlH4
NaBH4