oxidation of food Flashcards
oxidation
increase in oxygen to hydrogen ratio
- loss of hydrogen from a molecule or gain of oxygen
reduction
decrease in oxygen to hydrogen rato
aldehydes and ketones
molc containing carbonyl functional group (C=O)
antioxidants
molc that prevent unwanted oxidation reactions occurring
- easily oxidised substances
2 stages of primary alcohols being oxidised
- primary alc to aldehyde
- aldehyde to carboxylic acid
- primary to aldehyde
2 H molc from primary and 1 O molc moved to product forming aldehyde
- decrease in H atoms
- aldehyde to carboxylic acid
2 H from aldehyde and 1 O produce carboxylic acid with COOH
- increase in O atoms
aldehyde structure
- end in -al
- functional group CHO
- no need for number infront of -al in systematic name
- hydrogen bonded to carbonyl group unlike ketones
ketone structure
compound which contains the carbonyl group at a position within the hydrocarbon chain where all C atoms linked with single bonds
- CO
- contains position number before -one
how to distinguish between aldehydes and ketones
using 3 oxidising agents which will oxidise aldehyde but not ketone
- potassium dichromate
- fehling solution
- tollens regent
potassium dichromate
orange –> blue
fehlings solution
blue –> orange/red
tollens reagent
colourless –> silver