oxidation of alcohols Flashcards

1
Q

what is the general equation for the oxidation of alcohols?

A

alcohol + oxygen

makes an aldehyde,

if more oxygen is added, makes a carboxylic acid

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2
Q

what are 2 examples of oxidizing agents?

A
  1. potassium dichromate (K2Cr2O7)
  2. potassium manganate
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3
Q

what is another name for oxidation?

A

destructive oxidation

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4
Q

what is an aldehyde?

A

an organic compound in which the carbonyl group is attached to a carbon atom at the end of a carbon chain

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5
Q

what is a carboxylic acid?

A
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6
Q

what is the suffix for an aldehyde?

A

-al

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7
Q

what is the suffix for a carboxylic acid?

A

-oic acid

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8
Q

describe the oxidation process of methanol.

A

methanol - methanal - methanoic acid

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9
Q

why do we use potassium dichromate or potassium manganate as an oxidising agent?

A

because they have a lot of oxygens

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10
Q

what is the name of the apparatus for oxidation of alcohols?

A

a reflux apparatus

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11
Q

what is the difference between a reflux apparatus and a distillation apparatus?

A

reflux apparatus is set up to heat things but not let them escape, unlike distillation

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12
Q

describe the parts of a reflux apparatus

A

a round-bottomed flask with a condenser

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13
Q

why don’t we cover the reflux apparatus with a cork?

A

so it doesn’t explode!

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14
Q

describe the color change observed with when using an oxidizing agent of potassium dichromate

A

orange -> green

Cr(6+) -> Cr(3+)

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15
Q

describe the color change observed with when using an oxidizing agent of potassium manganate

A

purple -> pink

Mn(7+) -> Mn(2+)

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16
Q

what can ethanal be found in?

A

apples

17
Q

what is ethanoic acid found in?

A

vinegar

18
Q

acid + metal

A

salt + hydrogen

19
Q

acid + base

A

salt + water

20
Q

acid + metal carbonate

A

salt + water + carbon dioxide

21
Q

methanoic acid + sodium

A

sodium methanoate + hydrogen

22
Q
A