alkanes Flashcards
what does organic mean?
compounds that are based on carbon, with other elements such as hydrogen, oxygen, and nitrogen
what is a homologous series?
a group of chemicals/compounds with the same general formula, a pattern of physical properties, and similar chemical properties
what are hydrocarbons?
compounds consisting of only hydrogen and carbon
what are alkanes?
hydrocarbons with only single bonds
describe the naming system
root: based on the number of C atoms
suffix: homologous series
prefix: additional atoms
what is the structural formula of ethane?
(CH3)2
what is the structural formula of propane?
CH3CH2CH3
what is the structural formula of butane?
CH3CH2CH2CH3
OR
CH3(CH2)2CH3
What are the physical properties of alkanes (same as covalent discrete)?
Since they are covalent discrete:
- low melting point
- insulator
- soluble in oils, insoluble in water
describe the mpt/bpt of alkanes
mpt/bpt: from small molecules –> large molecules, INCREASES due to more IMFs
describe the viscosity of alkanes
viscosity: from small molecules –> large molecules, INCREASES due to more IMFs and larger molecules intertwine, like noodles
describe the volatility of alkanes
volatility: from small molecules –> large molecules, DECREASES due to increasing bpt
describe the colour of alkanes
colour: small molecules –> large molecules, COLOURLES-YELLOW-BLACK
what is viscosity?
resistance to liquid flow
what is volatility?
ease of turning into a gas
are alkanes generally unreactive or reactive and why?
generally unreactive, due to containing strong single bonds
what does saturated mean?
chemical only containing strong single bonds
how can we make alkanes react through energy?
in the form of:
- heat
- electricity
- light
IMPORTANT - what are the three types of reactions alkanes undergo?
ALKANES:
- SUBSTITUTION
- COMBUSTION
- DECOMPOSITION
what is the general equation for the combustion of alkanes?
Alkane + oxygen → carbon dioxide + water
what is the symbol equation for the combustion of methane?
CH4 (g) + 2O2 (g) → CO2 (g) + 2H2O (l)
what is the symbol equation for the combustion of ethane?
C2H6 (g) + 3½O2 (g) → 2CO2 (g) + 3H2O (l)
what is the symbol equation for the combustion of propane?
C3H8 (g) + 5O2 (g) → 3CO2 (g) + 4H2O (l)
what is the symbol equation for the combustion of butane?
C4H10 (g) + 6½O2 (g) → 4CO2 (g) + 5H2O (l)
what happens in the substitution of alkanes?
one atom (or group of atoms) is swapped with another atom (or group of atoms)
what needs to be present for alkanes to undergo substitution?
ultraviolet radiation (sunlight is a source of UV radiation) - this is the ACTIVATION ENERGY
does only one hydrogen atom always get substituted?
no, more than one hydrogen atom can be substituted depending on the amount of ultraviolet radiation there is
what is the general word equation for the substitution of alkanes with halogens?
alkane + halogen → halo alkane + hydrogen halide
what type of reaction is this, and what will it make?
ethane + chlorine
substitution of alkanes with halogens
chloroethane and hydrogen chloride
what type of reaction is this, and what will it make?
methane + bromine
substitution of alkanes with halogens
bromomethane + hydrogen bromide
what type of reaction is this, and what will it make?
propane + fluorine
substitution of alkanes with halogens
option 1: 1-fluoropropane
option 2: 2-fluoropropane
and hydrogen fluoride
how can we test which isomer we have if multiple can be made through a reaction?
using fractional distillation
what do we do if we have multiple prefixes in a name?
arrange them alphabetically, ignoring “di”, “tri”, “tetra”, etc.
what is complete combustion?
when there is excess/enough oxygen in a combustion reaction with an alkane
carbon dioxide and water are made from an alkane and oxygen
what is incomplete combustion?
when there is not enough oxygen during a combustion with alkane + oxygen
instead of carbon dioxide, it makes carbon monoxide and water, and soot
how do we avoid incomplete combustion?
by ventilation
why is soot bad?
it damages lungs, and damages machinery
what is cracking?
decomposition - breaking a large alkane into a smaller alkane and an alkene
what happens when we heat an alkane?
it decomposes to make a smaller alkane and an alkene
what conditions are needed for the decomposition of an alkane?
- approximately 300 degrees of heat
- a catalyst of Al2O3 or SiO2