Oxidation of Alcohols Flashcards
what is the oxidising agent used in the oxidation of alcohols
potassium dichromate(VI) K2Cr2O7
what is the colour change of the oxidation of alcohols
orange (Cr2O7 2-) dichromate (VI) ion
TO
green( Cr3+) chromium (III) ion
what are primary alcohols oxidised to
then what is that thing oxidised to
aldehyde
then FURTHER OXIDISED
to a carboxylic acid
what are secondary alcohols oxidised to
Ketones
what are tertiary alcohols oxidised to
THEY ARE NOT OXIDISEDDDDDDD
what is the functional group of an aldehyde, ketone, carboxylic acid
C=O
what is the general formula of an aldehyde and ketone
CnH2nO
what is the general formula of a carboxylic acid
CnH2n+1COOH
for aldehyde on what carbon is the functional group on ALWAYS
1st carbon
what are the oxidising agents used to DISTINGUISH between aldehydes and ketones
Fehling’s solution
tollens reagent
Fehling’s solution(Cu2+)
Fehling’s solution and benedict’s solution are both blue (CU2+)
which turn brick red when reduced (Cu2O) when warmed with an aldehyde, but STAYS blue with ketone
Tollens reagent [Ag(NH3)2]+
REDUCED to silver when warmed with an aldehyde
BUT not with a ketone.
the silver coats in the inside of the apparatus forming a silver mirror