Oxidation of Alcohols Flashcards

1
Q

what is the oxidising agent used in the oxidation of alcohols

A
potassium dichromate(VI)
K2Cr2O7
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2
Q

what is the colour change of the oxidation of alcohols

A

orange (Cr2O7 2-) dichromate (VI) ion
TO
green( Cr3+) chromium (III) ion

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3
Q

what are primary alcohols oxidised to

then what is that thing oxidised to

A

aldehyde
then FURTHER OXIDISED
to a carboxylic acid

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4
Q

what are secondary alcohols oxidised to

A

Ketones

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5
Q

what are tertiary alcohols oxidised to

A

THEY ARE NOT OXIDISEDDDDDDD

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6
Q

what is the functional group of an aldehyde, ketone, carboxylic acid

A

C=O

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7
Q

what is the general formula of an aldehyde and ketone

A

CnH2nO

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8
Q

what is the general formula of a carboxylic acid

A

CnH2n+1COOH

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9
Q

for aldehyde on what carbon is the functional group on ALWAYS

A

1st carbon

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10
Q

what are the oxidising agents used to DISTINGUISH between aldehydes and ketones

A

Fehling’s solution

tollens reagent

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11
Q

Fehling’s solution(Cu2+)

A

Fehling’s solution and benedict’s solution are both blue (CU2+)
which turn brick red when reduced (Cu2O) when warmed with an aldehyde, but STAYS blue with ketone

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12
Q

Tollens reagent [Ag(NH3)2]+

A

REDUCED to silver when warmed with an aldehyde
BUT not with a ketone.
the silver coats in the inside of the apparatus forming a silver mirror

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