Oxidation And Reduction Flashcards
Oxidation
(of an element) takes place when it loses electrons
Reduction
(of an element) takes place when it gains electrons
OILRIG stands for…
oxidation is loss
redcution is gain
an oxidising agent
is a substance that brings about oxidation in other substances
A reducing agent
is a substance that brings about reduction in other substances
Rule for assigning oxidation number to: Oxygen
Oxi number= -2
2 exceptions: H2O2 = -1 because it is an unusual compound
OF2 = +2 because fluorine is more electronegative than oxygen
Rule for assigning oxidation number to: Hydrogen
Oxi number = +1
Exceptions: metal hydroids (NaH, MgH2 etc) = -1
Reason: More electronegative than metals
Rule for assigning oxidation number to: Uncombined elements
Oxi number = 0
Rule for assigning oxidation number to: Simple ions
Cl-, Mg+2 etc Oxi number= charge on ion
Rule for assigning oxidation number to: Halogens (Group 7)
Oxi number = -1
Unless bonded with a more electronegative element
Rule for assigning oxidation number to: Compounds
The combined oxi numbers of all the elements = 0
H2SO4 -2 = 2+S-8=0 S= 6
Rule for assigning oxidation number to: Complex ions
The sum of the oxi numbers add to the charge on the complex ion
SO4 -2= S+4(-2) = -2 S= 6
If any situation doesn’t fit any of these rules…
Let the oxi number equal the charge on the ion the element would form ( K2PO4) O=-2 K is in group one so will lose one electron oxi number = +1 (2+P-8)= 0 P=6