Organometalic compound Flashcards
1
Q
Zeignar-natta catalyst
A
Al(Et)3 + TiCl4
2
Q
anti knocking agent in petrol
A
Pb(Et)4 (tetraethyl lead)
3
Q
Zeiser’s salt
A
K[PtCl3(C2H4)]
4
Q
η is used for
A
no. of carbon in π donor atoms
5
Q
Ferrocene
A
sandwich compound
[Fe(C5H5)2]
6
Q
-C5H5 as a ligand
A
cyclopentadienyl (tridented)
7
Q
sandwich compounds
A
ferrocene [Fe(C5H5)2] and [Cr(C6H6)2]
8
Q
types of organo metallic compound
A
- sigma
- pi bonded
- sigma and pi bonded (back bonding)
9
Q
sigma and pi bonded ex.
A
CO / CN- / NO+
10
Q
stronger the M-C bond (in M(CO))
A
weaker is the C-O bond
11
Q
in sigma and pi bonded ligand
A
sigma bond donates the electron by coordinate bond and pi bond accepts it.
12
Q
back bonding is also known as
A
synergic bonding
13
Q
structure of Mn2(CO)10
A
decacarbonyldimangnese(0)
14
Q
structure of Co2(CO)8
A
octacarbonyldicobalt
15
Q
Maximum coordination no (transitional metal)
A
6
