organics Flashcards

1
Q

recall atomic structure of carbon

A

Carbon has an atomic number 6 this is because it has 6 protons, as its an atom it contains 6 electrons these are arranged in two electron shells. The first shell contains 2 electrons, while the valence shell contains 4 electrons. and its covalent bonding

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2
Q

define a molecular formula

A

notation used to show the type and number of atoms in a molecule

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3
Q

define Condensed structural formula

A

notation used to show the type and number of atoms in a
molecule, with groups of atoms within the molecule written
separately

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4
Q

define Structural formula

A

drawing of a molecule, showing the type and number of atoms and how they are bonded

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5
Q

methane molecular formula alkanes

A

CH4

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6
Q

methane condensed structural formula alkanes

A

CH4

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7
Q

ethane molecular formula alkanes

A

C2H6

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8
Q

ethane condensed structural formula alkanes

A

CH3CH3

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9
Q

propane molecular formula alkanes

A

C3H8

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10
Q

propane condensed formula alkanes

A

CH3CH2CH3

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11
Q

butane molecular formula alkanes

A

C4H10

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12
Q

butane condensed structural formula alkanes

A

CH3CH2CH2CH3

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13
Q

pentane molcular formula alkanes

A

C5H12

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14
Q

pentane condensed structural formula alkanes

A

CH3CH2CH2CH2CH3

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15
Q

hexane molcular formula alkanes

A

C6H14

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16
Q

hexane condensed structural formula alkanes

A

CH3CH2CH2CH2CH2CH3

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17
Q

heptane molecular formula alkanes

A

C7H16

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18
Q

heptane condensed structural formula alkanes

A

CH3CH2CH2CH2CH2CH2CH3

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19
Q

octane molecular formula alkanes

A

C8H18

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20
Q

octane condensed structural formula alkanes

A

CH3CH2CH2CH2CH2CH2CH2CH3

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21
Q

define Homologous series

A

isa family with the same functional groups
E.g alkanes are single bonds, alkenes are double bonds and alcohols have an OH group

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22
Q

define Hydrocarbons

A

molecules that contain only carbon and hydrogen atoms. Examples: alkanes and alkenes.

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23
Q

Alkanes general formula:

A

CnH2n+2

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24
Q

Alkenes general formula:

A

CnH2n

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25
Alcohols general formula:
CnH2n+1OH
26
ethene molecular formula alkenes
C2H4
27
ethene condensed structural formula alkenes
CH2CH2
28
propene molecular formula alkenes
C3H6
29
propene condensed structural formula alkenes
CH2CHCH3
30
methanol molecular formula alcohols
CH3OH
31
methanol condensed structural formula alcohols
CH3OH
32
ethanol molecular formula alcohols
C2H5OH
33
ethanol condensed structural formula alcohols
CH3CH2OH
34
what does Saturated mean
Single bonds between carbon atoms
35
what does Unsaturated mean
Molecule contains at least one double or triple bond between 2 carbon atoms
36
define alkanes
alkanes are hydrocarbons, carbon atoms are covalently bonded with single bonds only, they are saturated
37
define alkenes
alkenes are hydrocarbons, Carbon atoms are covalently bonded with one or more double bonds. They are unsaturated
38
define alcohols
alcohols are NOT hydrocarbons - contain hydrogen, carbon AND oxygen atoms Carbon atoms are covalently bonded and contain one or more -OH groups.
39
define Solute
the solid substance being dissolved
40
define Solvent
the liquid that dissolves the solute
41
define Solution
when a solute dissolves in a solvent
42
define Soluble
a substance that can dissolve in a solvent
43
define Insoluble
a substance that cannot dissolve in a solvent
44
define Miscible
two liquids that can dissolve into each other
45
define Immiscible
two liquids that cannot dissolve into each other
46
define Volatile
easily turns from a liquid to a gas
47
link hydrocarbons room temp to melting and boiling point
eg. its 25 in a room but it boils at 30 so the hydrocarbon is just a liquid
48
differnces between complete and incomplete combustion
Complete combustion Excess oxygen Blue/colourless flame High temperature produced Produces CO2 and H2O only Incomplete combustion Limited supply of oxygen Orange flame Less heat produced Produces CO2, H2O, CO and C (soot) CO harmful - poisonous gas, binds to red blood cells, may cause death C harmful - inhaled, respiratory problems, damages the heart, known carcinogen.
49
effects on human health from incomplette combustion products
Carbon monoxide is dangerous because it is colourless, odourless and very toxic, since it competes with oxygen for the haemoglobin in the bloodstream. When carbon monoxide is inhaled and enters the bloodstream it binds with haemoglobin instead of oxygen. This causes a lack of oxygen in the cells, and causes body tissues and cells to die, leading to death.
50
effects on human health from soot
Soot (carbon) produced by incomplete combustion can cause breathing problems and can lead to lung cancer. It also damages the heart.
51
effects on enviroment from combustion products
The carbon dioxide formed by complete combustion of carbon compounds is a major greenhouse gas and contributes to global warming. The resulting rise in temperatures causes changing weather patterns and an associated impact on agriculture, including crop production, melting of the ice caps, a rise in ocean levels as warmer water expands, and loss of some species that are unable to adapt fast enough to the change in habitat.Loss of kelp in Punakaiki on the West Coast of the South Island in 2022 due to increased ocean temperatures.
52
what are three incomplete combustion products
carbon monoxide soot acid rain
53
how is acid rain made
when carbon dioxide dissolves into rainwater this makes carbonic acid so all rainwater is slightly acidic with a ph of 5, 5.5. but when nitrate and sulfate make it even more acidic, acid rain also adds to the acidity of ocean water
54
what is crude oil
a mixture of hydrocarbons over millions of years from dead animals and plants which without oxygen and high pressure and temperatures become an oil and stay liquid in underground reservoirs
55
what is fractional distillation
a process used to seperate crude oil based on their boiling points
55
how does fractional distillation work
crude oil is heated at super high temps and turned into a vapour, as the vapour rises through little holes in the trays the vapour is exposed to more and more air cooling down the vapour so once the crude oil gets to certain points if the temperature is lower then their boiling point the vapour condenses. larger alkanes with high boiling points condense at the bottoms and lower boiling point alkanes rise to the top more the alkanes put into fractions all have similar numbers of carbon atoms
56
what is the top fraction of factional distillation
refinery gases E.g methane, butane, propane these are used for fuels
57
what is the second from the top fraction in fractional distillation
petrol used as petrol
58
whats the third fraction from the top
Naptha, used for hydrocarbon cracking
59
whats the forth fraction from the top
kerosene, used for jet fuels
60
whats the fifth fraction from the top
disel used for disel
61
whats the sixth fraction from the top
Lubricant oil, used for cars and other machines
62
whats the seventh fraction from the top
fuel oil, used for ships
63
whats the lowest level fraction
residue, used to tarseal roads
64
define polymerisation
Joining a large number of small molecules (monomers) together to make a very large molecule.
65
what things does polymerisation need to work
Needs high temperature, pressure and a catalyst.
66
define cracking
breaking long chained molecules into shorter, and more useful, products such as petrol, or to make ethene that can then be made into plastics. The process involves high temperature, pressure and a catalyst.
67
word equation fro cracking decane
decane → octane + ethene
68
Balanced symbol equation for decane
C10H22 → C8H18 + C2H4
69
how do you draw a polymer chain
the carbon bond separates and the carbon can make single bonds each side
70
plastic is a polymer what is it used for
they are waterproof, insulators, strong but flexible and can be moulded into a variety of shapes which make them useful for things like plastic bags & bottles.
71
define combination reaction
Where two elements react to produce a single, more complex compound
72
define decompsition reaction
When a compound breaks down into its component elements or simpler compounds.
73
define thermal decomp
Reactions that involve the breaking down of a chemical substance by using strong heat.
74
define catyltic decomp
Reactions that involve the breaking down of a chemical substance using a catalyst
75
define precipitation reaction
Where two ionic solutions are mixed and an insoluble solid (precipitate) forms.
76
aluminium + iodine ------>
aluminium iodide
77
copper + oxygen --->
copper oxide
78
iron + chlorine ---->
iron chloride
79
iron + sulfur ----->
iron sulfide
80
magnesium + chlorine ---->
magnesium chloride
81
magnesium + oxygen ----->
magnesium oxide
82
sodium + chlorine →
sodium chloride
83
zinc + sulfur →
zinc sulfide
84
Metal elements react with non-metal elements to form ionic compounds what is needed for this to occur
heat
85
ionic compounds have electrostatic force why?
These strong electrostatic forces account for ionic solids having high melting and boiling points. It takes a lot of energy to break these strong forces. This is why most ionic compounds are solids at room temperature.
86
carbon + oxygen →
carbon dioxide
87
sulfur + oxygen →
sulfur dioxide
88
hydrogen + oxygen →
water
89
Non-metal elements react with non-metal elements to form covalent compounds, these need what to occur
heat
90
Bonds between atoms/within the molecule are??
Covalent bonds are very strong.
91
Most covalently bonded molecules are what at room temperature.
liquids or gases
92
define covalent bonds
atoms that share electrons form molecules
93
define ionic bonding
atoms that transfer electrons form ions
94
metal hydroxide ----->
metal oxide + water
95
metal carbonate ---->
metal oxide + carbon dioxide
96
metal hydrogen carbonate ------>
metal carbonate + carbon dioxide + water
97
whats the test for water
cobalt chloride paper Blue when it is dry, pink when it is wet/moist
98
what is the test for carbon dioxide
lime water Colourless at the start, cloudy/white when CO2 is present.
99
what is a catylst
Substance that increases the rate of a chemical reaction. It provides an alternate pathway with a lower activation energy for the reaction. It is not used up in the reaction and may be able to be reused.
100
hydrogen peroxide ---->
water + oxygen
101
combo raction word equation
a + b ----> ab
102
decomp reaction word equation
ab ----> a + b
103
precipitation rections are also sometimes called
double displacement reactions
104
precipitation reaction word equation
AB + CD ----> AD + CB
105
When writing ionic equations for precipitation reactions, only focus on what
the precipitate and the ions that form it!
106
why does a precipitate form?
A precipitate forms because the compound is insoluble, according to the Solubility Rules. If a compound is insoluble, it means that the attractions between the ions is greater than the attraction between the ions and the water molecules.