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CP > Organic Reactions > Flashcards

Organic Reactions Flashcards

1
Q

Hemiacetal formation

A
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2
Q

Hemiketal formation

A
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3
Q

Nucleophilic acyl substitution

A

Ex. serine acylation > ester

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4
Q

Serine Acylation

A
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5
Q

Carboxylic Acid Derivatives: Reactivity

A

(most reactive) acyl halides > anhydrides > esters/acids > amides (least reactive)

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6
Q

Reducing Agents

A

NADPH/NADH

LiAlH4

NaBH4 (weak - does not reduce carboxylic acids/esters)

DiBAlH

NiH2

PdH2

Fe2+

2-mercaptoethanol (denatures proteins by breaking disulfide bonds for SDS-PAGE)

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7
Q

Oxidizing Agents

A

PCC - weak (does not oxidize to carboxylic acids)

KMnO4

Na2Cr2O7

I2 & other halogens

H2O2

HNO3

NAD+

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8
Q
A
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CP (8 decks)

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