Organic Reactions Flashcards

1
Q

What is a substitution reaction

A

A hydrogen atom or functional group is replaced by another atom or molecule

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2
Q

What is a addition reaction

A

two or more molecules combine to go a larger one

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3
Q

What is a elimination reaction

A

The reverse of addition reaction

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4
Q

What is condensation reaction

A

Two molecules react to form a a larger molecule and another smaller one such as H20

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5
Q

What is oxidation reaction?

A

The addition of oxygen atoms or the removal of hydrogen atoms

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6
Q

What is a reduction reaction

A

The addition of hydrogen atoms or the removal of oxygen atoms (reverse of oxidation)

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7
Q

Which one of the homologous series can undergo combustion and substitution

A

Alkane

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8
Q

What is the difference between incomplete and complete combustion

A

During combustion when there is a limited oxygen supply, it is incomplete combustion, and CO or C is formed instead of carbon dioxide (complete combustion)

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9
Q

When an alkene C20H42 is heated with a catalyst under suitable conditions, 6 Ethane molecules and one other molecule is formed. What reaction has occurred

A

Catalyst cracking

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10
Q

What is formed during combustion of Alkanes

A

CO2/CO/C and water

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11
Q

What is the condition required for the substitution reaction of Alkane to occur

A

Presence of UV light

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12
Q

What is a halogen (used to react with alkanes in substitution reactions)

A

An organic compound where one or more H atoms is replaced by another atom like F Cl Br I etc

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13
Q

Name in order top to bottom products of fractional distillation of crude oil

A
Petroleum gas
Gasoline 
Naphtha
Paraffin 
Diesel oil
Lubricating oil
Bitumen
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14
Q

What is the catalyst for catalyst cracking?

A

Aluminum oxide or silicon IV oxide

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15
Q

What is the temperature for catalyst cracking of alkanes

A

600 degrees

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16
Q

What does catalyst cracking do

A

Converts long chains to short chains

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17
Q

What does combustion of alkanes produce

A

CO2 and H2O only

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18
Q

What are the three types of addition reaction

A

Addition of halogen
Addition of steam
Addition of hydrogen

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19
Q

What is the colour change in the addition of bromine reaction

A

Orange red colour will disappear as product formed is colour less

20
Q

What are the industrial level reagents and conditions for addition of steam to alkanes

A

300 degrees Celsius
60 bar pressure
Catalyst: concentrated phosphoric acid H3PO4

21
Q

What reaction allows alkenes to be converted to alkanes

A

Addition of hydrogen

22
Q

Reagents and conditions of addition of halogen to alkene

A

Halogen dissolved in CCl4, dark

23
Q

Reagents and conditions for addition of steam

A

1) Concentrated H2SO4 at room temp

2) add H2O, warm

24
Q

Reagents and conditions for Addition of hydrogen

A

H2 gas

Platinum catalyst

25
What is the colour test for double bonds/ unsaturated compounds/ alkenes
Orange aqueous bromine test that decolorizes when = present
26
What can the combustion of ethanol be used as?
Fuel as it produces a lot of heat
27
Reagents and conditions of elimination reaction for alcohol
Excess concentrated H2SO4 | 170 degrees
28
When will an elimination reaction in alcohols result in 2 possible alkene products
When the alcohol functional group is in the middle of the chain
29
What are the possible oxidising agents for oxidation of alcohols
Acidified potassium manganate (VII) | Acidified potassium dichromate (VI)
30
Reagents and conditions of oxidation of alcohols
KMnO4 / K2Cr2O7 H2SO4 (aq) Heat
31
What will oxidation of a primary alcohol form
A carboxylic acid
32
What will oxidation of a secondary alcohol form
A keto group
33
How many [O] is required for primary and secondary alcohol oxidation reactions respectively
2 and 1
34
What are the by products of elimination reactions
H2O
35
What are the by products of oxidation
H2O
36
What are the colour changes of the oxidising reagents of alcohols oxidation reaction
Purple-> decolourised KMnO4 | Orange -> green K2Cr2O7
37
What is the reaction between alcohols and carboxylic acid that forms esters
Condensation
38
What is one property of esters and what is its functional group
It is sweet smelling | -COO-
39
What is the catalyst of the condensation reaction that forms esters
Concentrated sulfuric acid
40
What is the bond created when an ester is formed
C-O-C^=O
41
State two ways ethanol can be prepared
Fermentation of glucose | Catalysts addition of steam to ethane laboratory
42
What are the reagents and conditions for addition of steam to ethane laboratory (industrial standards)
``` 300 degrees, 60 bar pressure Concentrated phosphoric (V) acid catalyst ```
43
A primary alcohol becomes a carboxylic acid after a reaction. What is it?
Oxidation with 2[O]
44
What is the ester of ethanol and propanoic acid
Ethyl props oate
45
What is the by product formed when an ester is formed?
Water