Organic Reaction Flashcards
Combustion
Hydrocarbons (and alcohols) burn in air to produce light/heat energy, CO2, and H2O
Complete Combustion
Oxidation
hydrocarbon + O2 = CO2 + H2O
Incomplete combustion
hydrocarbon + CO2 = C + CO + CO2 + H2O
Substitution
Replacement of hydrogen for a halogen atom or functional group in an alkane
What is required for a substitution to occur?
F2 is vigourous, Cl2 and Br2 need UV or heat
Aromatics require a catalyst
Halogenation
Replacement of one or more hydrogen atoms in an organic compound by a halogen (C-H bond broken, C-X formed)
alkane + halogen 2 + UV/heat
haloalkane (alkyl halide) + hydrogen halide
aromatic + halogen 2 + catalyst
haloaromatic + hydrogen halide
alcohol + hydrogen halide
haloalkane + water
haloalkane + base (NaOH)
alcohol + salt (Na halide)
Addition
Reaction of alkenes and alkynes where an atom (H or X) is added without the loss of a hydrogen atom
Double/triple bond is broken
Addition of Halogen
Halogenation
alkene + halogen 2 = haloalkane
Addition of Hydrogen
Hydrogenation
requires Pt catalyst, heat, and pressure
alkene + H2 = alkane