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Organic Conditions Flashcards

1
Q

What are the reagent for:

Nitrile to Amine

A

LiAlH4 or H2/Ni

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2
Q

What is the type of reaction for:

Nitrile to Amine

A

Reduction

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3
Q

What are the reagents and conditions for:

Haloalkane to Alkene

A

  • NaOH in ethanol*
  • Heat under reflux*
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4
Q

What are the type of reaction for:

Haloalkane to Alkene

A

Elimination

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5
Q

What are the reagents for:

Haloalkane to Nitrile

A

KCN

alcholic solution/reflux

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6
Q

What is the type of reaction for:

Haloalkane to Nitrile

A

Nucleophilic substitution

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7
Q

What are the conditions for:

Haloalkane to Primary Aimine

A

NH3 (excess)

alcholic solution/reflux

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8
Q

What is the type of reaction for:

Haloalkane to Primary Aimine

A

Nucleophilic substitution

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9
Q

What are the reagents/conditions for:

Ketone to Secondary Alcohol

A

NaBH4

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10
Q

What is the type of reaction for:

Ketone to Secondary Alcohol

A

Nucleophillic addition/Reduction

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11
Q

What are the reagents/conditions for:

Aldehyde to Primary Alcohol

A

NaBH4

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12
Q

What is the type of reaction for:

Aldehyde to Primary Alcohol

A

Nucleophillic addition/Reduction

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13
Q

What are the reagents/conditions reaction for:

Ester to Carboxylic Acid & Alcohol

A

H2O

Dilute H+ Catalyst/Reflux

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14
Q

What is the type of reaction for:

Ester to Carboxylic Acid & Alcohol

A

Hydrolysis

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15
Q

What are the conditions and type of reaction for:

Carboxylic Acid to Ester

A
  • Alcohol/Conc. H2SO4 catayst*
  • Reflux*

Esterification
NucleophillicAddition/Elimination

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16
Q

What are the Reagents of reaction for:

Aldehyde to Carboxylic Acid

A

  • H+/K2Cr2O7*
  • or Tollen’s*
  • or Fehlings*
17
Q

What is the type of the reaction:

Aldehyde to Carboxylic Acid

A

Oxidation

(via H+/K2Cr2O7, Tollen’s or Fehlings)

18
Q

What are the reagents of reaction for:

Secondary Alcohol to Ketone

A

H+/K2Cr2O7

19
Q

What is the type of reaction for:

Secondary Alcohol to Ketone

20
Q

What are the reagents and conditions of reaction for:

Primary Alcohol to Aldehyde

A
  • H+/K2Cr2O7*
  • Distillation*
21
Q

What is the type of reaction for:

Primary Alcohol to Aldehyde

A

Oxidation

(via H+/K2Cr2O7)

22
Q

What are the reagents and conditions of reaction for:

Alcohol to Alkene

A
  • conc. H2SO4*
  • reflux*
23
Q

What is the type of reaction for:

Alcohol to Alkene

A

Elimination

24
Q

What are the reagents and conditions of the reaction for:

Haloalkane to Alcohol

A
  • NaOH(aq)*
  • Warm/under reflux*
25
Q

What is the type of reaction for:

Haloalkane to Alcohol

A

Nucleophilic substitution

26
Q

What are the reagents and conditions of reaction for:

Alkene to Haloalkane

A

  • HBr*
  • Room temperature*
27
Q

What is the type of reaction for:

Alkene to Haloalkane

A

Electrophilic addition

28
Q

What are the conditions of reaction for:

Alkene to Polymer

A
  • High temp*
  • High pressure*
  • Catalyst*
29
Q

What is the type of the reaction for:

Alkene to Polymer

A

Addition polymerisation

30
Q

What is the type of reaction for:

Alkene to Alcohol

31
Q

What are the reagents and conditions of reaction for:

Alkene to Alcohol

A
  • Conc. H2SO4*
  • Steam: 300 oC*

Pressure: 60atm

32
Q

What are the reagents and conditions of reaction for:

Alkene to Dihaloalkane

A

  • Halide (e.g. BR2)*
  • Room temperature*
33
Q

What is the type of reaction for:

Alkene to Dihaloalkane

A

Electrophilic addition

34
Q

What are the reagents and conditions of reaction for:

Alkane to Haloalkane

A
  • Halide (e.g. Cl2)*
  • UV light & 1:1 ratio*
  • free radical substitution*
35
Q

What is the type of reaction for:

Alkane to Haloalkane

A

free radical substitution

Chemistry (2 decks)

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