Organic Chemistry - definitions Flashcards

1
Q

Bioalcohol

A

Fuels made from plant matter, often using enzymes or bacteria

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2
Q

Biodegradable

A

A polymer that can be broken down by microbes

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3
Q

Biodiesel

A

A fuel made from vegetable oils obtained from plants

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4
Q

Biofuel

A

Fuels obtained from living matter that has died recently

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5
Q

Carbocation

A

A positive ion in which the charge is shown on the carbon atom

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6
Q

Cracking

A

The breakdown of molecules into shorter ones by heating with a catalyst

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7
Q

Dehydration

A

The removal of the hydroxyl group in an alcohol molecule, together with a hydrogen atom from an adjacent carbon atom, forming a C=C bond

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8
Q

Diol

A

A compound containing 2 OH groups

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9
Q

Dipole

A

2 charges of equal magnitude but opposite signs are separated by a short distance

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10
Q

Displayed formula

A

Shows each bonding pair as a line drawn between the 2 atoms involved

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11
Q

Distillation with addition

A

Involves heating a reaction mixture, but adding another liquid and distilling off the product as it forms

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12
Q

Electrophile

A

An electron-deficient species attracted to a region of high electron density

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13
Q

Electrophilic addition

A

A reaction in which 2 molecules form one molecule and the attacking molecule is an electrophile

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14
Q

Elimination

A

A reaction in which a molecule loses atoms attached to adjacent carbon atoms, forming a C=C double bond

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15
Q

Ethanolic

A

A solution where ethanol is the solvent

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16
Q

Feedstock

A

Converting polymer waste into chemicals that can be used to make new polymers

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17
Q

Fractional distillation

A

The process used to separate a liquid mixture into fractions by boiling and condensing

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18
Q

Functional group

A

An atom or group of atoms in a molecule that is responsible for its chemical reactions

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19
Q

Geometric isomers

A

Compounds containing a C=C bond with atoms or groups of atoms attached at different positions

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20
Q

Halogenation

A

The addition of a halogen

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21
Q

Reflux

A

Heating a reaction mixture with a condenser fitted vertically, continuous evaporation and condensation

22
Q

Heterolytic fission

A

The breaking of a covalent bond so that both bonding electrons are taken by one atom

23
Q

Homolytic fission

A

The breaking of a covalent bond where each of the bonding electrons leaves with one species, forming a radical

24
Q

Hydration

A

The addition of water (steam)

25
Hydrocarbon
A compound that contains only carbon and hydrogen atoms
26
Hydrogenation
The addition of hydrogen
27
Hydrolysis
A reaction in which water hydroxide ions replace an atom in a molecule with an -OH group
28
Incomplete combustion
Some atoms in the fuel are not fully oxidised
29
Complete combustion
All the atoms in the fuel are completely oxidised
30
Initiation
The formation of radicals, usually as a result of bond breaking by ultraviolet radiation
31
Locant
A number used to indicate which carbon atom in the chain an atom or group of atoms is attached to
32
Mechanism
The sequence of steps in an overall reaction. Each step shows what happens to the electrons involved in bind breaking or bond formation
33
Nucleophile
An electron rich species that donates a lone pair of electrons to form a covalent bond with and electron-deficient atom
34
Nucleophilic Substitution
A reaction in which an attacking nucleophile replaces an existing atom or group in a molecule
35
Propagation
The two steps that, when repeated many times, convert the starting materials into the products of the reaction
36
Radical
A highly reactive species that contains unpaired electrons
37
Reforming
The conversion of straight-chain hydrocarbons into branched-chain and cyclic hydrocarbons
38
Restricted rotation
Fixes the position of the atoms or groups attached to C=C atoms around a C=C bond in a set space
39
Saturated
A compound containing only single bonds
40
Simple distillation
Used to separate liquids with very different boiling temperatures
41
Skeletal formula
Shows all the bonds between carbon atoms
42
Stereoisomers
Compounds with the same structural formula and the same molecular formula but with the atoms or groups arranged differently in 3D dimensions
43
Structural formula
Shows how atoms are joined together carbon-by-carbon
44
Structural isomers
Compounds with the same molecular formula but with different structural formulae
45
Substitution reaction
A reaction where an atom or group is replaced by another atom or group
46
Termination
The formation of a molecule from two radicals
47
Unsaturated
A compound containing one or more multiple bonds
48
Aliphatic
An organic compound that consists of carbon chains. These may be straight chains or cyclical. All electrons are fixed in covalent bonds.
49
Aromatic
An organic compound that contains a ring structure with delocalised electrons
50
Homologous series
A series of organic molecules that have the same general formula (functional group) that differ in successive members by CH2
51
Isomer
Organic compounds that have the same molecular formula but different structural formula (atoms are arranged in a different way)