Organic Chemistry Chapter 9 Flashcards

1
Q

What are Organic Compounds?

A

Compounds that contain carbon

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2
Q

What do organic compounds consist of?

A

Carbon backbone and one or more functional groups

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3
Q

What do hydrocarbon functional groups consist of?

A

Carbon and Hydrogen

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4
Q

What compounds do hydrocarbon functional groups consist of?

A

Alkanes
Alkenes
Alkynes
Aromatic Compounds

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5
Q

What is an Alkane?

A

Hydrocarbon that contains all single bonds

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6
Q

What is an Alkene?

A

Carbon-carbon double bond

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7
Q

What is an Alkyne?

A

Carbon-carbon triple bond

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8
Q

What is an aromatic functional group?

A

A benzene ring

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9
Q

What is an Alkyl Group?

A

An Alkane minus 1 hydrogen atom. They are “stick-on” groups appended to larger organic molecules. Represented as “R”.

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10
Q

What are alcohols and Ethers derived from?

A

Water

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11
Q

What is the Alcohol functional group?

A

Hydroxyl (OH) group.

(A generic alcohol may be represented as R-OH.

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12
Q

What is the Ether functional group?

A

Oxygen bonded to 2 alkyl groups

(A generic Ether may be represented as R-O-R)

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13
Q

What is the functional group of an Alkyl Halide?

A

Halogen Atom (F, Cl, Br, I)

Generic alkyl halides may be represented as “X” so may be represented as R-X.

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14
Q

What are many inhaled anesthetic reagents composed of?

A

Alkyl Halides with Ether functional groups

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15
Q

What are Amines derived from?

A

Ammonia, in which one or more of the hydrogens on ammonia have been replaced by alkyl groups.

(Example of Generic Amines: RNH2, R2NH, R3N)

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16
Q

What is the Carbonal group?

A

Carbon double bonded to an Oxygen.

17
Q

What are the carbonyl-based functional groups?

A

Aldehydes
Ketones
Carboxylic Acids
Esters
Amides

18
Q

What is an Aldehyde?

A

Hydrogen atom bonded to a carbonyl group

Ex: R(C=O)OH (Can also be written as RCO2H or RCOOH

19
Q

What is a Ketone?

A

2 Alkyl groups bonded to a carbonal group.

Ex: R2C=O

20
Q

What is a Carboxylic Acid?

A

Hydroxyl group bonded to a carbonyl group

Ex: RCO2H or RCOOH

21
Q

What is an Ester?

A

Alkoxy (OR) group bonded to Carbonyl Group

Ex: R(C=O)OR, RCO2R or RCOOR.

22
Q

What are Esters condensation products of?

A

Carboxylic Acid and Alcohol.

RCO2H+ROH—>RCO2R+H2O

23
Q

What is an Amide?

A

Nitrogen atom bonded to a carbonyl group.

Ex: R(C=O)NR2.

24
Q

What is the “R” group on Nitrogen of an Amide?

A

Alkyl groups or hydrogens

25
Q

What are Amides condensation products between?

A

Carboxylic Acid and an Alcohol.

Ex: RCO2H + R2NH —> R(C=O)NR2 + H2O.

26
Q

Aldehydes and ketones undergo addition reactions with_________ to form_________?

A

Alcohols
Hemiacetal/Hemiketal

27
Q

The functional group of a hemiacetal/hemiketal is characterized by which 2 functional groups on the same carbon?

A

Ether Functional Group and Alcohol functional group on the same carbon

R2C = O + R’OH —> R2C(OH)R’

28
Q

In the presence of excess alcohol (and an acid catalyst), aldehydes and ketones condense with 2 alcohol molecules to form what?

A

Acetals or ketals

29
Q
A