Organic Chemistry Flashcards

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1
Q

Organic

A

carbon containing compounds

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2
Q

Carbon can covalently bond to up to ___ other atoms

A

4

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3
Q

What composes the backbone?

A

Carbon

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4
Q

Hydrocarbons

A
  • only carbon and hydrogen

* release energy when oxidized

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5
Q

Hydroxyl

A

-OH (or HO-)
•Alcohols
•Polar because it is hydrophilic
•Hydrogen bonds

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6
Q

Carbonyl

A

C=O
•Terminal (on the end of a chain)- aldehyde
•Non-terminal – ketone
•In sugars

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7
Q

Carboxyl

A
O=C-OH
•acidic- can donate a proton 
•polar
•Carbonyl plus hydroxyl 
•Acts as an acid because the hydrogen can be donated to an acid, ionizing
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8
Q

Amino

A

H-N-H
•Acts as a base
•Can pick up an H⁺

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9
Q

Sulfhydryl

A

-SH
• Tends to confer polarity to that part of molecule
• In cross linking proteins (reactions between separate parts of the protein making a bridge)
• Confers polarity in some molecules

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10
Q

Methyl

A
CH₃
• Generally not very reactive
• In gene expression
• If DNA gene has a methyl to it, it determines whether the gene is expressed or not.
	◦ Can depend on environmental factors
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11
Q

Phosphate

A
  • Confers a negative charge to molecules, can sometimes neutralize
  • Can be removed from a water molecule, then theres a release of energy
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12
Q

Isomers of organic molecules. Structural:

A

Structural: Same molecular formula but different covalent arrangements of atoms

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13
Q

Isomers of organic molecules. Geometric:

A

Geometric: same covalent arrangements, different spatial arrangements
•cis double bonds tend to put kinks in biological molecules ( or some parts)

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14
Q

Isomers of organic molecules. Enantiomers:

A

Enantiomers
•mirror images of each other
•In molecules where one carbon has four different groups attached (asymmetric carbon)
•Many biological reactions are specific to one enantiomer
•Enantiomers of a drug may have different effects

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15
Q

Polymers

A

Large molecules (polymers) - with repeating subunits (monomers)

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16
Q

Polymerization

A
  • Enzyme catalyzed ( in biological systems)
  • Energy input
  • Dehydration
  • Also called condensation
17
Q

Hydrolysis of polymers

A

Hydro- water
Lysis – decomposition or breakdown
• Adding water breaks apart the Hydrogen and the Hydroxyl
•Enzymes often called hydrolases

18
Q

Functions of proteins

A
Enzymatic
Defensive
Storage
Transport
Hormonal
Receptor
Contractile and motor
Structural