Organic Chemistry Flashcards
Organic
carbon containing compounds
Carbon can covalently bond to up to ___ other atoms
4
What composes the backbone?
Carbon
Hydrocarbons
- only carbon and hydrogen
* release energy when oxidized
Hydroxyl
-OH (or HO-)
•Alcohols
•Polar because it is hydrophilic
•Hydrogen bonds
Carbonyl
C=O
•Terminal (on the end of a chain)- aldehyde
•Non-terminal – ketone
•In sugars
Carboxyl
O=C-OH •acidic- can donate a proton •polar •Carbonyl plus hydroxyl •Acts as an acid because the hydrogen can be donated to an acid, ionizing
Amino
H-N-H
•Acts as a base
•Can pick up an H⁺
Sulfhydryl
-SH
• Tends to confer polarity to that part of molecule
• In cross linking proteins (reactions between separate parts of the protein making a bridge)
• Confers polarity in some molecules
Methyl
CH₃ • Generally not very reactive • In gene expression • If DNA gene has a methyl to it, it determines whether the gene is expressed or not. ◦ Can depend on environmental factors
Phosphate
- Confers a negative charge to molecules, can sometimes neutralize
- Can be removed from a water molecule, then theres a release of energy
Isomers of organic molecules. Structural:
Structural: Same molecular formula but different covalent arrangements of atoms
Isomers of organic molecules. Geometric:
Geometric: same covalent arrangements, different spatial arrangements
•cis double bonds tend to put kinks in biological molecules ( or some parts)
Isomers of organic molecules. Enantiomers:
Enantiomers
•mirror images of each other
•In molecules where one carbon has four different groups attached (asymmetric carbon)
•Many biological reactions are specific to one enantiomer
•Enantiomers of a drug may have different effects
Polymers
Large molecules (polymers) - with repeating subunits (monomers)