Acids, Bases, and Buffers (Intro) Flashcards
What charge does water have and why?
Water is a “polar” molecule, meaning that there is an uneven distribution of electron density. Water has a partial negative charge near the oxygen atom due the unshared pairs of electrons, and partial positive charges near the hydrogen atoms.
The ability of ions and other molecules to dissolve in water is due to
polarity
Unique physical properties due to hydrogen bonding
high heat of vaporization, strong surface tension, high specific heat, and nearly universal solvent properties of water
H+ in regards to acids and bases
Acids release H⁺, bases accept H⁺
Alcohol
hydrocarbon with a hydrogen replaced by “OH”
Acid
hydrocarbon with a hydrogen replaced by a carboxyl “COOH”.
COOH -> COO⁻ + H⁺
Amine
hydrocarbon with a hydrogen replaced by an amine “NH₂”. Basic- accepts protons. NH₂ + H⁺ -> NH₃⁺
Phosphate
addition of -PO₄⁼ (switch)
Amino Acid
hydrocarbon with amino and carboxyl groups
The pH of a solution indicates
how much acid (acidity) or base (alkalinity) exists in a solution
An acid is….
a substance that increases the concentration of hydrogen ions (H⁺) in a solution, usually by having one of its hydrogen atoms dissociate
A base…
provides either hydroxide ions (OH⁻) or other negatively charged ions that combine with hydrogen ions, reducing their concentration in the solution and thereby raising the pH. In cases where the base releases hydroxide ions, these ions bind to free hydrogen ions, generating new water molecules
The stronger the acid, the more readily it donates
H⁺
Strong bases are those substances that readily donate
OH⁻ or take up hydrogen ions
Buffers…
readily absorb excess H⁺ or OH⁻, keeping the pH of the body carefully maintained in the narrow range required for survival