Organic Chemistry Flashcards

1
Q

What is cracking

A

Heating longer chains of hydrocarbon to make shorter chains

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2
Q

What is an isomer

A

Molecules with the same molecular formula but different structural formula

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3
Q

What is an unsaturated molecule

A

Molecules that contain one or more double bonds

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4
Q

Wht is a saturated molecules

A

Hydrocarbons that contain only single bonds between carbon atoms

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5
Q

What is the formula for complete combustion

A

Hydrocarbon+oxygen> carbon dioxide + water

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6
Q

What are the products of incomplete combustion and their faults

A

Carbon monoxide- binds to the haemoglobin in the blood where oxygen is meant to bind, leading to fainting, coma or death. It is colourless and odorless

Particulates/soot- Leads to global dimming, and respiratory problems if inhaled

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7
Q

What is the bromine water test

A

The bromine water test is use to identify between saturated (alkanes) and unsaturated (alkenes) hydrocarbons.

Add orange bromine water to the hydrocarbon sample and shake the test tube gently.

Alkanes do not react so if the solution stays orange, it is saturated (alkane).

If the solution turns colourless, alkenes are present and the molecule is unsaturated

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8
Q

Is an alkane saturated or unsaturated

A

Saturated (single bonds)

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9
Q

Is an alkene saturated or unsaturated

A

Unsaturated (double bonds)

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10
Q

what is the homologous series

A

A series of organic compounds that have the same general formula and similar chemical properties.
These include:
alkanes
alkenes
alcohols
carboxylic acids

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11
Q

What are the two types of cracking

A

Catalytic cracking
Steam cracking

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12
Q

Explain catalytic cracking

A

The hydrocarbon is heated until it’s vaporised (a gas).

Put the gas in contact with the catalyst (hot powdered aluminium oxide)

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13
Q

Explain steam cracking

A

Heat the hydrocarbon to make it a gas then heat again at very high temperatures causing the chains to break down

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14
Q

What’s the word equation for cracking

A

Long chain alkane > shorter alkane + Alkene

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15
Q

What do we do with the alkenes that are formed from cracking

A

We can use them to form polymers and can use them to produce other chemicals

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16
Q

What is a cation

A

A positively charged ion

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17
Q

Are cations usually metals or non metals and what is the one exception

A

They are usually metals as metals form positive ions.
Ammonium ion NH4 is a non metal cation.

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18
Q

What are the two groups of tests for cations

A

The flame tests
The metal hydroxide tests

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19
Q

Describe the flame test

A

Take a platinum wire loop and clean it by dipping it in some dilute hydrochloric acid, rinsing it in distilled water and heating it over a bunsen burner flame.

Dip the wire loop in the compound you want to test.

Hold the loop wire in the clear part of the blue flame (this is the hottest part).

See what colour the flame turns as the compound burns.

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20
Q

What colour does lithium ions turn when burning

A

red

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21
Q

What colour does sodium ions turn when burning

A

yellow

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22
Q

What colour does potassium ions turn when burning

A

lilac

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23
Q

What colour does calcium ions turn when burning

A

orange/red

24
Q

What colour does copper ions turn when burning

A

green/blue

25
What is a limitation of the flame test
If you have two or more different metals in your sample, then the colours will mix together so you won’t be able to tell which metals you have.
26
What is the metal hydroxide test
We react metals with a solution of sodium hydroxide and see what colour the solution turns. This is possible because some metal ions form coloured precipitates when reacting with hydroxide ions
27
When reacting with sodium hydroxide what colour does copper form
Blue colour. (copper hydroxide is formed and a blue colour is seen.)
28
When reacting with sodium hydroxide what colour does calcium form
white precipitate
29
When reacting with sodium hydroxide what colour does iron form
Green precipitate
30
When reacting with sodium hydroxide what colour does iron (FE3+) form
brown precipitate
31
When reacting with sodium hydroxide what colour does magnesium form
white precipitate
32
When reacting with sodium hydroxide what colour does aluminium form
forms a white precipitate but if there is excess it redissolves to form colourless solution
33
What is an anion
A negatively charged ion
34
What is the carbon dioxide test
Put the gas in a test tube and connect it using a rubber tube to another test tube of limewater. If it turns cloudy carbon dioxide is present
35
What is the test for sulfphates
Add dilute hydrochloric acid to the test tube and add barium ions. If a white precipitate is seen, sulphur is present
36
What is the test for halide ions
Add dilute nitric acid. to remove impurities Add silver nitrate. If it reacts with chloride ions a white precipitate is formed If it reacts with bromide ions a cream precipitate is formed If it reacts with iodide ions a yellow precipitate is formed
37
Why use flame photometry
It can detect individual wavelengths that are emitted from different ions The intensity of the line on the spectrum indicates the concentration of the ion If a sample contains different ions the spectrum will show lines for all of them Very accurate very fast
38
As the length of the carbon chain in alkanes increases, what happens to the boiling point
Increases
39
Longer alkanes with more than 4 carbons are what state at room temperature
liquids
40
As the chain (number of carbons) increases in alkanes do they become more or less viscous
More viscous (sticky and thick)
41
As the chain (number of carbons) increases in alkanes do they become more or less volatile
less volatile (how easy it is to evaporate)
42
Shorter alkanes are easy to burn, they are more..
flammable
43
shorter alkanes are great for
fuels
44
What does the carbon carbon double bond in an alkene do
Allows Addition reactions to take place. Opens up allowing atoms of another molecule to bond with the carbon
45
What is the functional group for alcohol
-OH (hydroxyl)
46
Alcohols burn in oxygen to form what
CO2 and H2O
47
What are two properties of alcohol
soluble in water Used as fuels, solvents, and in alcoholic drinks
48
How is ethanol produced
Fermentation. Hydration of ethene (ethene +steam)
49
what is the functional group of carboxylic acids
-COOH
50
properties of carboxylic acids
Weak acids (do not fully ionise in water) react with carbonates to produce CO2 salt and water React with alcohols to form esters
51
What is condensation polymerisation
When monomers join and produce a smaller molecule like water
52
What is addition polymerisation
When monomers join to form polymers
53
What is hydrogenation
Where hydrogen is added to an unsaturated compound, like an alkene to convert it into a saturated compound
54
What two conditions are needed for fermentation
Warm temp of 25-40 sterile conditions
55