Organic Chemistry Flashcards

1
Q

What is Organic Chemistry

A

Chemistry involving hydrocarbons; or molecules w/ mostly C and H atoms

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2
Q

Ways to draw organic compounds

A

Formula (C6H14)
Lewis structure (H3C-CH2-CH2-CH2-CH2-CH3
Skeletal structure using lines for bonds and vertexes/points for carbons

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3
Q

What are Isomers

A

Organic compounds with the same formula but different arrangement of atoms

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4
Q

What are the different types of isomers

A

Structural, positional, functional group, chain and stereoisomers

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5
Q

Stereo isomers

A

Molecules which have the same atoms connected to each other but different arrangements in space (Are 3D)

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6
Q

Geometric isomers

A

Isomers w/ double or triple bonds which differ in the arrangements in space and can’t be moved much like singe bonds can

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7
Q

Cis

A

A compound with functional groups of chains on the same side

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8
Q

Trans

A

A compound with functional groups of chains on opposite sides

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9
Q

Structural isomer

A

Changes the structure of the compound

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10
Q

Positional isomer

A

Changes functional group position
(From 1,2 to 1,3 Dibromopropane)

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11
Q

Functional group isomer

A

Changes type of functional group(s)
(Same elements, diff functional groups)

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12
Q

Optical isomers

A

A carbon with 4 functional groups that can form an isomer where the images cannot overlay

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13
Q

What is Infrared Spectroscopy

A

An interaction between matter and light (Electromagnetic radiation) that shows what type of functional groups a compound has

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14
Q

What trends show up on an infrared spectrum for different functional groups

A

C-H bond: 2850-3100; deep straight dip
O-H bond: 2500-3650 ; deep, wide, and curved dip
C=O bond: 1640-1759
C and triple bonded N: 2200-2250
Carbon ring: less than 1200; many narrow and deep dips

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15
Q

What is the substitition reaction of alkanes

A

Free radical substitution

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16
Q

Steps to a free radical substitution

A

Step 0, Initiation step, Propagation step, and Termination step

17
Q

What are free radical(s)

A

Atoms or molecules with an unpaired electron

18
Q

What is a saturated hydrocarbon?

A

A hydrocarbon w/ only single bonds
(C — C)

19
Q

What are unsaturated hydrocarbons?

A

Hydrocarbons with two double bonded carbons (C=C)

20
Q

What is an empirical formula? At

A

Shows the simplest whole number ratio of atoms of each element in the compound (Ex. H2O, HO2CCO2H, CaC2O4)

21
Q

KMnO4 is…

A

Potassium Maganate (Adds oxygen/ oxidizes a compound)

22
Q

Energy change formula = ?

A

mc delta T

23
Q

How are orbitals in an atom organized?

A

Different layers around the nucleus called electron shells, each growing bigger in size and energy the farther away from the nucleus

24
Q

Shell levels are organized how?

A

1st shell - Contain 2 electrons and only 1s

2nd shell - Contain 8 electrons, has one 2s orbital and a three 2p orbitals

3rd shell - Contains 8 but can also hold up to 18, has a 3s, three 3p orbitals, and five 3D orbitals

25
Q

What’s the order of energy orbitals from least to greatest?

A

1s(2), 2s, 2p(6), 3s, 3p, 4s, 3d(10), 4p, 5s, 4d, 5p, 6s, 4f (14), 5d, 6p, 5f, 6d, 6f