Organic Chemistry Flashcards

1
Q

What is Organic Chemistry

A

Chemistry involving hydrocarbons; or molecules w/ mostly C and H atoms

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2
Q

Ways to draw organic compounds

A

Formula (C6H14)
Lewis structure (H3C-CH2-CH2-CH2-CH2-CH3
Skeletal structure using lines for bonds and vertexes/points for carbons

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3
Q

What are Isomers

A

Organic compounds with the same formula but different arrangement of atoms

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4
Q

What are the different types of isomers

A

Structural, positional, functional group, chain and stereoisomers

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5
Q

Stereo isomers

A

Molecules which have the same atoms connected to each other but different arrangements in space (Are 3D)

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6
Q

Geometric isomers

A

Isomers w/ double or triple bonds which differ in the arrangements in space and can’t be moved much like singe bonds can

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7
Q

Cis

A

A compound with functional groups of chains on the same side

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8
Q

Trans

A

A compound with functional groups of chains on opposite sides

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9
Q

Structural isomer

A

Changes the structure of the compound

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10
Q

Positional isomer

A

Changes functional group position
(From 1,2 to 1,3 Dibromopropane)

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11
Q

Functional group isomer

A

Changes type of functional group(s)
(Same elements, diff functional groups)

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12
Q

Optical isomers

A

A carbon with 4 functional groups that can form an isomer where the images cannot overlay

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13
Q

What is Infrared Spectroscopy

A

An interaction between matter and light (Electromagnetic radiation) that shows what type of functional groups a compound has

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14
Q

What trends show up on an infrared spectrum for different functional groups

A

C-H bond: 2850-3100; deep straight dip
O-H bond: 2500-3650 ; deep, wide, and curved dip
C=O bond: 1640-1759
C and triple bonded N: 2200-2250
Carbon ring: less than 1200; many narrow and deep dips

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15
Q

What is the substitition reaction of alkanes

A

Free radical substitution

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16
Q

Steps to a free radical substitution

A

Step 0, Initiation step, Propagation step, and Termination step

17
Q

What are free radical(s)

A

Atoms or molecules with an unpaired electron

18
Q

What is a saturated hydrocarbon?

A

A hydrocarbon w/ only single bonds
(C — C)

19
Q

What are unsaturated hydrocarbons?

A

Hydrocarbons with two double bonded carbons (C=C)

20
Q

What is an empirical formula? At

A

Shows the simplest whole number ratio of atoms of each element in the compound (Ex. H2O, HO2CCO2H, CaC2O4)

21
Q

KMnO4 is…

A

Potassium Maganate (Adds oxygen/ oxidizes a compound)

22
Q

Energy change formula = ?

A

mc delta T

23
Q

How are orbitals in an atom organized?

A

Different layers around the nucleus called electron shells, each growing bigger in size and energy the farther away from the nucleus

24
Q

Shell levels are organized how?

A

1st shell - Contain 2 electrons and only 1s

2nd shell - Contain 8 electrons, has one 2s orbital and a three 2p orbitals

3rd shell - Contains 8 but can also hold up to 18, has a 3s, three 3p orbitals, and five 3D orbitals

25
What’s the order of energy orbitals from least to greatest?
1s(2), 2s, 2p(6), 3s, 3p, 4s, 3d(10), 4p, 5s, 4d, 5p, 6s, 4f (14), 5d, 6p, 5f, 6d, 6f