Organic Chemistry Flashcards
homologous series
family of similar compounds
functional groups
atom/ group of atoms that determines the chemical properties of the compound
general formulae of alkenes
CnH2n
general formulae of alkanes
CnH2n+2
are alkenes saturated or unsaturated
unsaturated
are alkanes saturated or unsaturated
saturated
as chain length increases…
- intermolecular forces between molecules become stronger
- melting and boiling point increase
- viscosity increases
- volatility decreases
condition for alkanes and chlorine to react
UV light
bromine and alkenes reaction
orange to colourless
bromine with alkanes reaction
stays orange
what are fuels
chemical substance that releases energy when burned
main fossil fuels
natural gas, petroleum, coal
main component of natural gas
methane
what is a hydrocarbon
compound made up of hydrogen and carbon atoms only
process of frac. distillation of petroleum
- petroleum is heated and pumped into bottom of distillation fraction
- molecules with less carbon atoms have lower boiling points and evaporate first and rise
- the top is much cooler, so it will condense back into a liquid and is collected
- hydrocarbons with more carbon atoms have higher boiling point, it condenses at a higher temp., midway along the tower and is collected
what is a fraction
group of hydrocarbons with similar chain length
fractions list
- refinery gas
- gasoline
- naphtha
- paraffin
- diesel oil
- fuel oil
- lubricating fraction
- bitumen
refinery gas
bottles gases for cooking and heating
gasoline
car fuel
naphtha
starting point for chemical reactions
paraffin/ kerosene
fuel for aircrafts, lamps and oil stoves
diesel oil
fuel for diesel engines
fuel oil
fuel for power stations, ships and home heating systems
lubricating fraction
oil for car engines, machinery, waxes and polishes
bitumen
road surfaces and roofs
example of substitution reaction
alkanes and chlorine
incomplete combustion
burns with lack of oxygen and produces poisonous carbon monoxide and soot
why is carbon monoxide toxic
bind irreversibly to haemoglobin and prevents it from carrying oxygen
substitution reaction
- atom(s) are replaced by different atom(s)
- makes chloroalkanes
- needs UV light to provide activation energy
- photochemical reaction (needs light)
cracking
- chemical process that breaks down longer chain alkane molecules into smaller alkane and alkene molecules (which are more useful)
conditions for cracking
- catalyst
- high temperature
use for alkenes made from cracking
- fuels
(flow and ignite more easily)
reaction that makes one product
addition
reaction with hydrogen and alkenes
hydrogenation
(makes margarine)
reaction with steam and alkenes
hydration
(used as solvent or disinfectant)
reaction with bromine and alkenes
brown –> colourless