Organic chemistry Flashcards

1
Q

What are hydro-carbons

A

= molecules which only contain carbon and hydrogen atoms

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2
Q

What is a homologous series

A

= group of organic molecules with similar chemical properties
- all compounds in a homologous series have the same gen. formula

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3
Q

What are functional groups

A

= atoms responsible 4 characteristic reactions of a particular compound. Members of the same homologous series belong to same f. group.

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4
Q

What are alkanes

A

= saturated hydrocarbons -> carbon atoms joined by single bonds (c-c)

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5
Q

Alkanes general formula

A

C(n)H(2n+2)

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6
Q

What are alkenes

A

= unsaturated hydrocarbons -> some of their carbon atoms are joined by a double bond
(c=c)

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7
Q

What is fractional distillation

A

= separates a mixture into a number of different parts, called fractions -> substances with high boiling points condense at the bottom and lower boiling point condense on the way to the top

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8
Q

What are boiling points

A

-> smaller the molecule, smaller the boiling point b/c dec. intermolecular forces b/n molecules t/f dec energy needed 2 break them.

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9
Q

What is viscosity

A

= measure a fluid’s resistance 2 flow

longer carbon chains = higher viscosity

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10
Q

What is cracking

A

= breakdown of large hydrocarbon molecules into smaller molecules using a catalyst

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11
Q

What is a catalyst

A

-> refers 2 a substance used 2 decrease the activation energy in a reaction

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12
Q

What is the cracking method

A

1) heating mineral-wool soaked in oil with a catalyst, producing a gas
2) oil will likely be a long chain hydrocarbon, the catalyst is heated and not the oil b/c the oil = flammable
3) the product being gaseous suggests we have produced molecules with a smaller size than that of the oil

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13
Q

What is complete combustion

A

= compounds of hydrogen + carbon only. When burned -

  • > carbon oxidises 2 become CO2
  • > hydrogen oxidises 2 become H2O

(hydrocarbon + oxygen -> carbon dioxide + water)

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14
Q

What is incomplete combustion

A

= occurs when supply of air or oxygen is poor. Water is still produced but carbon monoxide and carbon are produced instead of co2

(hydrocarbon + oxygen -> c/co/co2 + water)

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15
Q

What is a substitution reaction

A

= 1 atom swapped with another
Alkanes undergo a substitution reaction with halogens in the presence of UV light

(alkanes + hydrogen –(light)–> alkanes)

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16
Q

What is an addition reaction

A

= The presence of c=c bond allows 4 inc. complex reactions 2 take place.
Alkanes can react with dif. types of chemicals during addition reaction

17
Q

Addition reaction: Bromine water

A
  • Bromine water use 2 distinguish alkanes + alkynes
  • X change when alkane added to water
  • Bromine water becomes colourless from orange-brown when mixed with an alkene
18
Q

Addition reaction: Hydrogenation

A
  • Alkenes can react with dif types of chemicals during addition reactions

(Alkene + hydrogen –(catalyst)–> Alkane)

-> needs a catlayst

19
Q

Addition reaction: Hydration

A

= need 2 be temp of 300 degrees C + catalyst

Alkene + water(steam) –(300degC, catalyst)–> alcohol

20
Q

How to produce ethanol

A

1) hydration
2) fermentation

(look in notes 4 pos + neg of each)