organic chemistry Flashcards
what are tetrahedral carbons
> they have only single bonds
tetrahedral in shape
alkanes, chloroalkanes and alcohols are examples of tetrahedral compounds
they are used as fuels and solvents
what are planar carbons
> has double or triple bond
two dimensional
double and triple bonds prevent rotation
alkynes and alkenes are typical examples
true or false molecules can have planar parts and tetrahedral parts
TRUE
what is a hydrocarbon
contains C and H only
what are saturated bonds and examples
only have single carbon to carbon covalent bond
e.g. alkanes, chloroalkanes, alcohols
what are unsaturated bond and examples
contains at least one double or triple carbon to carbon bonds
e.g. alkenes and alkynes
what does the test for unsaturation do
it turns bromine water from red to colourless or acidified KMnO4 from purple to colourless
what is the solubility of the Polar OH group
this can lead to hydrogen bonding
soluble in polar solvents -water
insoluble in non polar solvents -cyclohexane and benzene
boiling point and melting point higher than expected for molecular mass due to increased intermolecular attraction caused by polar group
what is caused by presence of Polar C to O group
does not lead to hydrogen bonding
soluble in polar solvents-water
insoluble in non polar solvents-cyclohexane and benzene
boiling point and melting point higher than expected for molecular mass due to increased intermolecular attraction caused by the polar group
production and use of alkanes
production
- crude petroleum
- natural gas
- decomposing organic matter
uses
fuel
production and use of alkenes
production
C2H5OH=C2H4+H2O(Al2O3)
uses
-making plastics
production and use of alkenes
production
C2H5OH=C2H4+H2O(Al2O3)
uses
-making plastics
production and uses of alkynes
production
CaC2+2H2O=C2H2+Ca(OH)2
uses
-fuel
production and uses of alcohol
production
-C6H12O6=2C2H5OH+2CO2(zymase yeast)
uses
- beverage
- solvent
- fuel
production and uses of aldehydes
production
-primary excess alcohol/remove immediately
uses
- making plastics
- fuel
production and uses of ketones
production
-propan-2-ol (secondary alcohol) reflux
uses
-solvents
production and uses of carboxylic acids
production
-dichromate in excess/reflux/then distil
uses
- condiment
- solvent
- cellulose acetate
- food preservatives
production and uses of esters
production
C2H5OH+CH3COOH=CH3COOC2H5+H2O
uses
- solvents
- flavours
hydrocarbon
made of Carbon and Hydrogen only
Aliphatic
consists of chains of carbons
what is the general formula for alkanes
CnH2n+2
what are alkanes
- they are saturated hydrocarbons
- they are aliphatic e.g. consist of chains
- they are non polar so insoluble in water
- sources include crude petroleum, natural gas and decomposing plant matter
- they are separated by fractional distillation
- they are our main source of fuels
what are chloroalkanes used for
-used as solvents and also flame retardants when fully halogenated e.g. CCI4 and CFCs
what is the general formula for Alkenes
CnH2n
name and formulas of Alkenes
> ethene C2H4
propene C3H6
butene C4H8