DEFINITIONS Flashcards
acid -bronsted lowry
proton H+ donor
acid -arrhenius
produces H+( hydrogen ion) by dissociated in water (aqueous solution)
acidic oxide
oxide that lowers pH in water
activation energy
minimum energy needed for colliding particles to react
addition polymerisation
monomers combining to form a large molecule
absorption
the method of attachment of gaseous or liquid molecules to solid surface
AAS- atomic absorption spectrometry
instrumental method used to analyse water for heavy metals
atomic number
number of protons in nucleus
BOD - biochemical oxygen demand
amount of oxygen consumed in p.p.m. (mg1-1) when sample kept in dark for 5 days at 20C
atomic orbital
region around nucleus in which there is high probability of finding electron
atomic radius
half the distance between the centres of singly bonded atoms of the same element
atomic sub level
a sub division of a main energy level consisting of one or more orbitals of the same energy
auto ignition
tendency to premature ignition
avogadros law
equal volumes of gases contain equal numbers of molecules under same conditions of temperature and pressure
base-arrhenius
produces OH- as only an ion in aqueous solution
base -bronsted lowry
proton H+ acceptor
bond energy
average energy required to break 1 mole of bonds into separate atoms in the gaseous state
boyles law
PV=k at constant temperature
catalyst
substance that alters rate of reaction and is not used up
catalytic cracking
splitting of long chain molecules by heat and catalyst
catalytic poison
substance that blocks the active site of a catalyst and stops it working
charles law
V/T=k at constant pressure
chemical equilibrium
state in which rate of forward reaction = rate of reverse reaction
chromatography
separation of a mixture of components based on their relative attractions for a stationary phase while carried in a mobile phase
Condensation reaction
Production of a more complex molecule with formation of an unsaturated compound (or double bond) by the loss of a small molecule
Conjugate acid (bronsted Lowry)
Produced by gain of one proton (H+)
Conjugate pair
Acid base differing by proton
Covalent bond
Involving the sharing of one or more pairs of electrons
Crystals
Regular solids made up of particles (atoms,ions,molecules) with fades intersecting at iced (definite, specific, characteristic) angles or consisting of particles in a lattice
Dobereiners triads
Elements of similar properties in groups of three
Dynamic
Reaction has not stopped
Effective collision
One that results in a reaction
Electrolysis
Chemical reaction caused by electric current passing through an electrolyte
Electronegativity
Measure of relative attraction for shared electrons
Element
An element cannot be broken down into anything simpler
Energy level
Shell which electrons of equal energy can occupy
Equilibrium
Rate of forward reaction = rate of reverse reaction
Eutrophication
Excess plant growth caused by excess nutrient in water
Excited state
Higher energy state or in n > 1 level (shell)
Feedstock
Modified and purified raw materials
First ionisation energy
Minimum energy to remove most loosely bound electron from an isolated gaseous atom in its ground state
Flocculation
The clumping of suspended solids
gay lussacs law
the volumes measured at the same temperature and pressure of reacting gases and their gaseous products are in small whole number ratios
greenhouse factor
stating its influence on the green house effect compared with carbon dioxide
greenhouse effect
blocking the escape of radiation by gases in the atmosphere
greenhouse gas
atmospheric gas that prevents escape of heat
ground state
in lowest energy state or in n = 1 level (shell)
half life
time taken for half of the nuclei in a sample to decay
hard water
does not form a lather with soap
forms scum with soap
soft water
forms a lather with soap
temporary hardness
removed by boiling caused by calcium (magnesium) hydrogencarbonate
hardness
not removed by boiling caused by calcium or magnesium chloride or sulphate
heat of combustion
heat change when one mole of a substance is burned completely in excess oxygen
heat of formation
heat change when one mole of a compound formed from its elements in their standard states
heat of reaction
heat change when the number of moles of reactants in the balanced equation react completely
heinsbergs uncertainty principle
it is not possible to measure the exact position and velocity of electron in atom at same time
hetrogeneous catalyst
reactants and catalyst in different phases
homogeneous catalyst
reactants and catalyst in the same phase
hydrocarbon
compounds composed of hydrogen and carbon only
ideal gas
a gas the that obeys the gas laws at all values of temperature and pressure
immiscible liquids
do not mix or do not dissolve in each other
isomers
compounds with same molecular formula but different structural formula
isotopes
atoms of same element with different mass numbers due to different number of neutrons
intermolecular
forces between molecules
intramolecular
forces between atoms in a molecule
Kw
(H+)(OH-)
le chateliers principle
reactions at equilibrium oppose applied stressed
limiting reagent
substance that is totally consumed when chemical reaction is complete
mole
contains the avogadros number (61023) of particles or relative molecular mass in grams
mass number
number or protons and neutrons in the atom of an isotope
nitrogen fixation
conversion of atmospheric nitrogen to compound that can be used by plants
octane number
measure of the tendency of a fuel to auto ignite
orbital
region in which electron is likely to be found
oxidation
loss of electrons or increase in oxidation number
pH
-log10(H3O+)
Pi Bond
side on overlap of p orbitals
primary standard
pure, stable, high molecular mass substance from which solutions of known concentration can be made
primary treatment
removal of solids by screening and settlement (sedimentation)
radioactivity
spontaneous breaking up of a nucleus to release a,b or y radiation
rate of a chemical reaction
change in concentration of reactant or product per unit time
reduction
gain of electrons or increase in oxidation number
relative atomic mass
average mass of atoms of element relative 1/12 mass of carbon atom or isotope
reversible
can go in both directions
scrubbing
method of removing pollutants from industrial chimney gases
secondary treatment (sewage)
biological oxidation
sigma bond
head on (end on) overlap of orbitals
standardised
concentration got by another titration (or colorimetry or u.v. spectroscopy)
strong acid -bronsted lowry
good proton donor
strong acid- arrhenius
completely dissociate into ions in dilute aqueous solution
structural isomer
compounds having the same molecular formula but different structural formulas
sub level
a sub division of a main energy level consisting of one or more orbitals of the same energy
tertiary treatment (of sewage)
removal of nitrogen compounds (nitrates) and phosphorus compounds (phosphates)
unsaturated
having at least one carbon to carbon double or triple bond
volatile
easily vaporised
weak acid -bronsted lowry
poor proton donor
weak acid -arrhenius
lightly dissociates into H3O+ ions in dilute aqueous solution