Organic Chem

Question 1

Friedrich Wohler

Answer 1

Discovered Urea disproving vitality theory; Ammonium cyanate + heat = Urea

Question 2

Jans Jacob Berzelius

Answer 2

Isomerism

Question 3

Adolph Wilhelm Hermann Kolbe

Answer 3

carbon disulfide –> acetic acid; total disproval of vitalism

Question 4

Linus Pauling

Answer 4

constituted resonance

Question 5

August Kekule

Answer 5

cyclic form of benzene, C atom form 4 bonds to form long chain

Question 6

Gilbert Lewis

Answer 6

Lewis Structure, covalent bonding, octet rule

Question 7

Robert Robinson

Answer 7

focused in the movement of e- in order to show that it is the driving force of chm rxn

Question 8

Difference of Lewis Structure and Resonance

Answer 8

Lewis structure: localization of e-
Resonance: Delocalization of e-

Question 9

Lewis Structures

Answer 9

E- are shared or unshared

Question 10

Resonances

Answer 10

e- are shared by several nuclei and redistributed for more stable arrangement

Question 11

Formal Charge

Answer 11

Overall charge considering all

Question 12

Isomer

Answer 12

different compounds that has same molecular formula

Question 13

Constitutional Isomers

Answer 13

compounds whose atoms are bonded differently

Question 14

Stereoisomers

Answer 14

compounds whose atoms are oriented differently

Question 15

Enantiomers

Answer 15

Stereoisomers that are mirror images but not superimposable

Question 16

Diastereomers

Answer 16

Stereoisomers that are not mirror images of one another

Question 17

Aleipar

Answer 17

Greek Fat

Question 18

Alkane

Answer 18

Paraffin; parum affinis: low affinity

Question 19

Alkenes

Answer 19

Olefins

Question 20

Alkynes

Answer 20

CnH2n-2

Question 21

Alkenes

Answer 21

CnH2n

Question 22

Contributing Structures

Answer 22

representation of diff Lewis structures

Question 23

Resonant Hybrid

Answer 23

combination of two resonance hybrid