organic chem 👩‍🔬 Flashcards

1
Q

what is homolytic fission

A

breaking of a covalent bond such that one electron goes to each of the atoms, forming free radicals

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2
Q

what is heterolytic fission

A

breaking of a covalent bond such that both the electrons go to the same atom, forming positive and negative ions

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3
Q

definition of constitutional (structural) isomerism

A

same molecular formula but different structural formula

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4
Q

what is enantiomerism

A

same molecular formula and structural formula but with different arrangement of atoms

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5
Q

define what is a free radical

A

an atom or molecule having an unpaired electron ➡️ electron deficient and is unstable because it is very energetic and has high tendency to pair up with another radical to complete its octet of electrons

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6
Q

what are the problems with FRS

A
  1. multi substitution
  2. production of isomeric products
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