Organic . Flashcards

1
Q

A sigma bond (single bond) is the lowest energy, strongest, most stable type of bond COVALENT BONDS. [S Orbital]

A

A Pi Bond is a double bond between two atoms. [ One S orbital and One P orbital ]

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2
Q

KNOW THAT

A

Single Bonds are the longest and easiest to break; double bonds are shorter and harder to break; triple bonds are the shortest and most difficult to break .

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3
Q

Nucleophilic Functional Groups

A

have a partial NEGATIVE charge and seek POSITIVE charged Nuclei

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4
Q

Electrophilic Functional Groups

A

have a partial POSITIVE charge and seek electrons , normally get attacked.

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5
Q

Enantiomers

A

Mirror images , same molecular formula and connectivity, but differ in configuration.
Rotate plane-polarized light in opposite directions to an equal degree.

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6
Q

Absolute Configuration (R, S)

A

the highest priority is given to the atom with the largest atomic weight . (outside of fluorine)

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7
Q

The direct and Number of degrees that the electric field is rotated when it passes through a compound

A

observed rotation

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8
Q

Diastereomers

A

have the same molecular formula, same bond to bond connectivity , but aren’t mirror images of each other and are not the same compound .

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9
Q

Anomers

A

cyclic diasterteomers that are formed when a ring closure occurs at an epimeric carbon ( differ at only one chiral carbon)

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