Organic Flashcards
Define empirical formula
The simplest whole number ratio of atoms in a molecule
Define molecular formula
Gives the actual number of atoms of different elements in a molecule
Define displayed formula
Shows every atom and every bond in a molecule
Define structural formula
Shows arrangement of atoms in a molecule without showing every bond
Define skeletal formula
Drawn as lines with each vertex being a carbon atom. Carbon atoms not drawn, assumed each atom has all unspecified bonds as C-H
Give the suffixes for:
An alkane
An alkene
An alcohol
An aldehyde
A ketone
A carboxylic acid
-ane
-ene
-ol
-al
-one
-oic acid
Give the prefixes for:
CH3 group
C2H5 group
C3H7 group
C4H9 group
Cl group
Br group
I group
•Methyl-
•Ethyl-
•Propyl-
•Butyl-
•Chloro-
•Bromo-
•Iodo-
Define structural isomerism
When molecules have the same molecular formula but different structural formula
What is positional isomerism?
Functional group is attached to the main chain at a different place
What is functional group isomerism?
Same atoms but different functional group due to a different arrangement of atoms
What is a chain isomerism?
Hydrocarbon chain organised differently e.g branched chains
Define stereoisomerism
When molecules have the same structural and molecular formula, but have a different arrangement of atoms in space
What is E-Z isomerism?
Is caused by the limited rotation about c=c double bonds
How are E and Z isomers decided?
If the 2 substituents with the highest molecular formula mass are on same side of double bond, it is the Z (zusammen) isomer
If they’re on different sides it is the E (entgegen) isomer
What is an alkane?
A saturated hydrocarbons containing C-H bonds only
What’s the general formula of an alkane?
CnH2n+2
Are the bonds in alkanes polar/non polar? Why?
Non-polar: Carbon and hydrogen have similar electronegativities
Which intermolecular forces do alkanes have and why?
Only VDW forces of attraction as bonds are non-polar
Are alkanes soluble in water? Why?
Insoluble as hydrogen bonds in water are stronger than alkanes’ VDW forces of attraction
How reactive are alkanes?
Very unreactive
Which reactions will alkanes undergo?
Combustion and reaction with halogens
What is crude oil?
Mixture of fractions (hydrocarbons with similar boiling points and properties)
How is crude oil formed? Is it renewable?
Formed at high temps and pressures deep below earth’s surface over millions of years
Therefore non renewable
Name the fractions from high to low boiling points
Gases - fuel on site
Gasoline/petrol/naphtha - cars
Kerosene/paraffin - jet fuel, lighting
Diesel oil - lorries/taxis
Lubricating oil/waxes - candles, engine oil
Fuel oil - ships, power stations
Tar/bitumen - roads/roofing
What is fractional distillation?/how does it work?
crude oil heated until mostly vaporised
Passed into a fractionating tower thats cooler at top than the bottom
liquid fractions are piped off the at the bottom
Vapours rise up the column & -via trays&bubblecaps- condense when temp<their boiling point
Shortest chain hydrocarbons condense at top as they have lowest bpt
What is fracking and how is it done?
Natural gas held within shale rock
Drill into shale, force pressurised water and sand into rock to fracture it, collect gas
HCl and methanol added to break up shale and prevent corrosion
What are the advantages of fracking?
Gas supply for many years
Reduces imported gas and electricity
What are the disadvantages of fracking?
Lots of traffic to the local area
Concern about amount of water used
Chemical additives can pollute water supplies
Can cause small earthquakes
Combust CH4->CO2->global warming
Why are alkanes cracked?
To turn a long chain alkane (not economically viable) into a shorter chain alkane and an alkene (more reactive, starting point for many products)
Why is a shorter chain alkane more economically viable?
As they can be used as a fuel
What are the conditions for thermal cracking?
700-1200 K temperature
Up to 7000kPa pressure
What is the intermediate for the reaction?
Free radicals
What are the main products for thermal cracking?
alkenes
What are the conditions for catalytic cracking?
Lower temp (720K)
Lower pressure (but above atmospheric)
Zeolite catalyst (SiO2 and Al2O3) with a honeycomb structure to give a large surface area
What are the main products of catalytic cracking?
Cycloalkanes, aromatic hydrocarbons, branched alkanes
Write an equation for the combustion of propane
C3H8 + 5O2 —> 3CO2 + 4H2O
What is a fuel?
Something which releases heat energy when combusted
What are the 5 main fuels comprising of alkanes?
Methane, Butane, Propane, petrol (about C8), paraffin (C10-C18)
What is incomplete combustion? What products are formed in the case of alkanes?
Combustion in a limited supply of oxygen
CO - carbon monoxide- poisonous
C - carbon - soot - global dimming
Which type of hydrocarbons are most likely to undergo incomplete combustion?
Longer chains
What is the environmental impact of carbon monoxide?
It’s toxic/poisonous
What is the environmental impact of nitrogen oxides?
Forms nitric acid -> acid rain, photochemical smog
What is the environmental impact of sulfur impurities/ sulfur dioxide?
Forms sulphuric acid -> acid rain
What is the environmental impact of soot (carbon)?
asthma, global dimming, cancer
What is the environmental impact of unburnt hydrocarbons?
Photochemical smog
What is the environmental impact of carbon dioxide?
greenhouse gas-> global warming,
increases local temperatures,
speeds up climate change
What is the environmental impact of water vapour?
greenhouse gas-> global warming,
increases local temperatures,
speeds up climate change
What are flue gases?
Gases given out by power stations
Write 2 equations for 2 different ways of desulfurising flue gases
CaO(s)+2H2O(l)+SO2(g)+1/2O2(g)—> CaSO4 2H2O(s)
or
CaCO3(s)+SO2(g)+1/2O2(g)—> CaSO4+CO2(g)
What are catalytic converters made up of?
Ceramic honeycomb coated with platinum, palladium and rhodium metals
What do catalytic converters catalyse (equations)?
They catalyse these reactions of products from car exhausts
2CO(g)+2NO(g)—>N2(g)+2CO2(g)
Hydrocarbons+NO—>N2+CO2+H2O
What are greenhouse gases?
Gases which trap infrared radiation, making the earth act like a greenhouse
What is the greenhouse effect and how does it contribute to global warming?
Greenhouse gases trap infrared radiation in atmosphere, atmosphere heats up —> global warming
Define carbon neutral activities?
Activities that produce no net/overall carbon dioxide emissions
How are halogenoalkanes formed from alkanes?
Free radical substitution reaction
What are the 3 stages of free radical substitution?
•Initiation-breaking halogen bond to form free radicals
•Propagation-chain part of the reaction where products are formed but free radical remains
•Termination-free radicals removed, stable products formed
What are the conditions needed for the formation of a free radical chlorine atom?
Presence of UV light
Write equations for the reaction of CH4 with Cl2 to form CH3Cl
initiation:Cl2–>2Cl• (in presence of UV light)
propagation:Cl•+CH4–>HCl+•CH3
•CH3+Cl2–>CH3Cl+Cl•
Termination: •CH3+Cl•->CH3Cl
2Cl•->Cl2
•CH3+•CH3->CH3CH3
What is the ozone layer’s function?
Protects the earth from harmful exposure too too many UV rays
How do CFC’s break the ozone layer down?
Free radical substitution
Write an equation for the overall decomposition of ozone into oxygen (O2)
2O3 —> 3O2
Write free radical substitution equations to show how Cl free radicals catalyse the decomposition of O3
Cl2 -> 2Cl (in presence of UV light)
Cl•+O3 -> ClO•+O2
ClO•+O3 -> 2O2+Cl•
Overall: 2O3 -> 3O2
Are halogenoalkanes soluble in water?
Insoluble as C-H bonds are non-polar, not compensated for enough by C-X bond polarity
Do halogenoalkanes have a polar bond? Why?
Yes polar, as halogen has a higher electronegativity than C (halogen os delta-, Carbon is delta+)
Which intermolecular forces do halogenoalkanes have? Why?
Permanent dipole-dipole and VDW forces of attraction
C-X bond polarity creates permanent dipoles
When would halogenoalkanes have higher melting points?
Increase Carbon chain length
Halogen further down group 7
How would the mass of a haloalkane compare with the mass of an alkane of the same chain length?
Greater because mass of halogen > mass of H
What is the most important in determining haloalkanes reactivity?
Carbon-halogen bond enthalpy
What is the order of reactivity of halogenoalkanes?
Although C-F is most polar bond, the bond enthalpy of C-X decreases down the group so reactivity increases down the group
What is a nucleophile?
A negatively charged ion/delta- atom with a lone pair of electrons which can be donated to an electron deficient atom
Give 3 examples of nucleophiles
:OH-
:CN-
:NH3