Amount of Substance Flashcards

1
Q

Define Relative Atomic Mass

A

The mean mass of an atom of an element,divided by 1/12 of the mean mass of an atom of the carbon-12 isotope

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2
Q

Define Relative Molecular Mass

A

The mean mass of a molecule of a compound,divided by 1/12 of the mean mass of an atom of the carbon-12 isotope

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3
Q

What is Avogadro’s constant?

A

6.022 x 10^23

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4
Q

What does Avogadro’s constant allow you to find?

A

The number of particles present in a sample of a substance with known mass
Number of particles=nL
n=moles L=Avogadro constant

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5
Q

What does the number in Avogadro’s constant allow you to find?

A

The number of particles present in a sample of a substance with known mass
Number of particles = nL
(n=moles)(L=Avogadro’s constant)

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6
Q

How do you calculate moles?

A

Mass/Mr
Concentration x volume/1000

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7
Q

What trends do gases and volatile liquids follow when under standard conditions?

A

Pressure is proportional to temperature
Volume is proportional to temperature
Pressure and volume is inversely proportional

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8
Q

What is the ideal gas equation?

A

pV=nRT=mRT/Mr

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9
Q

What are the standard units for the ideal question?

A

p=pressure in pascals
V=volume measured in m³
T=Temperature in Kelvin
n=moles
m=mass in grams

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10
Q

What is the ideal gas constant? What is it equal to?

A

R
It is equal to 8.31JK-¹mol-¹

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11
Q

What is the empirical formula?

A

The simplest whole number ratio of atoms of each element in a compound

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12
Q

How is empirical formula found?

A

Using molar ratios of each element

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13
Q

What is molecular formula?

A

The true number of each atom in the molecule

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14
Q

How can molecular formula be determined?

A

Using the Mr of the empirical formula and the true Mr of the molecule.
This gives a multiplier value which can be used to scale up the empirical formula

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15
Q

What must chemical equations be before they are used in calculations?

A

Balanced

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16
Q

Why must equations be balanced before being used in calculations?

A

The reacting ratios must be correct

17
Q

How do you calculate percentage yield?

A

%yield=Experimental yield/Theoretical mass x 100

18
Q

How do you calculate atom economy?

A

%atom economy=Mr or desired product/Mr of reactants x 100

19
Q

In industrial processes, why is it desirable to have a high atom economy for a reaction?

A

There is little or no waste product, only the desired product. The process is more economically viable for industrial scale manufacture

20
Q

Why is a high atom economy beneficial for the environment?

A

It uses less natural resources and therefore uses less energy

21
Q

What is Boyle’s Law?

A

At constant temperature then the product of pressure and volume is constant
P x V = constant

22
Q

What is Charle’s Law?

A

At constant pressure then volume is proportional to the temperature
VαT
V/T = Constant

23
Q

What is Gay-Lussac’s Law?

A

At constant volume, pressure is proportional to the temperature
PαT
P/T = Constant

24
Q

What is the yield of a reaction?

A

The mass of product obtained

25
Q

What is the theoretical yield?

A

The maximum theoretical mass of product in a reaction (calculated using the idea of conservation of mass)

26
Q

What is the actual yield?

A

The mass of product you get when you actually do the reaction

27
Q

What is the percentage yield?

A

The ratio of actual mass of products obtained compared with maximum theoretical mass

28
Q

What is a titration used to measure?

A

An unknown concentration of solution by reacting it to a known concentration of another solution