Optical, Thermal and Electrical Properties Used to Characterize Dental Materials Flashcards

1
Q

physical properties

A

optical properties
thermal properties
electrical properties

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2
Q

optical properties

A

color and pigmentation
opacity
refractive index

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3
Q

thermal properties

A

temperature
heat of fusion
thermal conductivity
specific heat
thermal diffusivity
coefficient of thermal expansion

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4
Q

electrical properties

A

electrical conductivity
dielectric constant
electromotive force
galvanism
corrosion

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5
Q

light interacting with surface occurs through

A

reflection: angle of incidence equals angle of reflection, diffuse reflection
absorption: angle of incidence absorbed into material
refraction: angle of incidence different from angle of refraction

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6
Q

three components of color

A

dominant wavelength: perceived color

luminous reflectance: B-W (light diffusing objects), B-Clear (transmitting objects)

excitation purity: saturation of color

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7
Q

color can be measured

A

instrumentally (spectrophotometer) or visually

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8
Q

pigmentation

A

esthetic process used in restorations
addition of incorporating colored pigments in non-metallic materials
observed color results from selective absorption by the pigments and reflection of certain colors

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9
Q

surface roughness

A

influences how material will interact with its environment
Atomic Force Microscopy (AFM) can be used to map these areas of roughness

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10
Q

surface wetting

A

the ability of a liquid to maintain contact with a solid surface
a result of intermolecular forces and determined by adhesion and cohesion forces

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11
Q

cohesive forces

A

causes the liquid to ball up and avoid contact with the surface

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12
Q

adhesive forces

A

interaction between liquid and solid that causes liquid to spread across the surface

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13
Q

surface wetting - contact angle

A

contact angle > 90 deg - hydrophobic
contact angle < 90 deg - hydrophilic

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14
Q

fluorescence

A

emission of light from a material that has absorbed light
generally has a lower energy emitted than absorbed
natural human teeth emit fluorescent light when excited by UV radiation
some restorations add fluorescing materials to reproduce natural appearance of tooth

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15
Q

opacity

A

material property that prevents the passage of light

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16
Q

translucency

A

permits the passage of light but disperses it

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17
Q

transparency

A

permits the passage of light with little distortion

18
Q

refractive index

A

ratio of the velocity of light to its velocity in a medium
light slows from its speed in air and may change direction

19
Q

temperature

A

measured using a thermocouple or thermometer
consideration for dental work: measurement of heat during cavity shaping, increase in temperature during tooth cutting

20
Q

differential scanning calorimetry

A

used to locate transition temperatures and study effects on material
determines heats of transition and reaction

21
Q

thermal gravimetric analysis

A

can measure the mass loss as a function of temp

22
Q

thermomechanical analysis

A

measures dimensional change with or without an applied load

23
Q

glass transition temperature Tg

A

reversible transition in amorphous materials from a hard state to a more flexible state with increased temperature

24
Q

temperature of crystallization Tc

A

after a Tg, the amorphous material is less viscous, there may be a rearrangement of molecules into a crystalline state, resulting in an exothermic peak

25
Q

melting temperature TM

A

with increased temperature, the sample reaches its melting point, resulting in an endothermic peak

26
Q

differential scanning calorimetry (DSC)

A

used to locate transition temperatures and study effects on material

27
Q

heat/enthalpy of fusion

A

the quantity of heat to convert 1g of a material from solid to liquid with no temperature change

28
Q

thermal conductivity

A

the quantity of heat required per second to pass through 1 cm material with a cross sectional area of 1 cm2

29
Q

metals have much _____ thermal conductivity than non-metals

A

higher

30
Q

specific heat capacity

A

quantity of heat needed to raise the temperature of 1 gram of material one degree

31
Q

relationship of metals and specific heat capacity

A

metals have low specific heat because they require less heat to warm
also give up their heat quickly

32
Q

thermal diffusivity

A

the rate of heat transfer through a medium
significant difference between metal and ceramic values

33
Q

coefficient of thermal expansion

A

the rate at which a material expands during temperature change

34
Q

thermal expansion of restoration in tooth

A

no heat: restoration expands more than tooth, wedging and extrusion

heat applied: restoration expands less than tooth, loosening and gap formation

35
Q

electrical conductivity

A

the ability to conduct an electric current and is governed by Ohm’s Law
ceramics are not good conductors, called insulators

36
Q

electrical resistivity

A

the resistance to passing electric current
the resistivity of a homogenous conductor varies directly with its length and cross-sectional area

37
Q

resistance and resistivity are proportional based on the

A

length and size of the material

38
Q

dielectric material

A

provides electrical insulation but can be polarized in an electric field

39
Q

electromotive force emf

A

metals and alloys used in dental restorations are susceptible to corrosion
is a listing in order of their decreasing tendency to oxidize in solution

40
Q

bimetallic corrosion/galvanism

A

two dissimilar filling materials in opposing teeth have a difference in emf
the saliva can act as an electrolyte
if the flow of current goes through the patients pulp, pain is experienced and the anodic restoration may corrode