Optical, Thermal and Electrical Properties Used to Characterize Dental Materials Flashcards

1
Q

physical properties

A

optical properties
thermal properties
electrical properties

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2
Q

optical properties

A

color and pigmentation
opacity
refractive index

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3
Q

thermal properties

A

temperature
heat of fusion
thermal conductivity
specific heat
thermal diffusivity
coefficient of thermal expansion

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4
Q

electrical properties

A

electrical conductivity
dielectric constant
electromotive force
galvanism
corrosion

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5
Q

light interacting with surface occurs through

A

reflection: angle of incidence equals angle of reflection, diffuse reflection
absorption: angle of incidence absorbed into material
refraction: angle of incidence different from angle of refraction

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6
Q

three components of color

A

dominant wavelength: perceived color

luminous reflectance: B-W (light diffusing objects), B-Clear (transmitting objects)

excitation purity: saturation of color

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7
Q

color can be measured

A

instrumentally (spectrophotometer) or visually

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8
Q

pigmentation

A

esthetic process used in restorations
addition of incorporating colored pigments in non-metallic materials
observed color results from selective absorption by the pigments and reflection of certain colors

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9
Q

surface roughness

A

influences how material will interact with its environment
Atomic Force Microscopy (AFM) can be used to map these areas of roughness

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10
Q

surface wetting

A

the ability of a liquid to maintain contact with a solid surface
a result of intermolecular forces and determined by adhesion and cohesion forces

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11
Q

cohesive forces

A

causes the liquid to ball up and avoid contact with the surface

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12
Q

adhesive forces

A

interaction between liquid and solid that causes liquid to spread across the surface

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13
Q

surface wetting - contact angle

A

contact angle > 90 deg - hydrophobic
contact angle < 90 deg - hydrophilic

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14
Q

fluorescence

A

emission of light from a material that has absorbed light
generally has a lower energy emitted than absorbed
natural human teeth emit fluorescent light when excited by UV radiation
some restorations add fluorescing materials to reproduce natural appearance of tooth

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15
Q

opacity

A

material property that prevents the passage of light

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16
Q

translucency

A

permits the passage of light but disperses it

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17
Q

transparency

A

permits the passage of light with little distortion

18
Q

refractive index

A

ratio of the velocity of light to its velocity in a medium
light slows from its speed in air and may change direction

19
Q

temperature

A

measured using a thermocouple or thermometer
consideration for dental work: measurement of heat during cavity shaping, increase in temperature during tooth cutting

20
Q

differential scanning calorimetry

A

used to locate transition temperatures and study effects on material
determines heats of transition and reaction

21
Q

thermal gravimetric analysis

A

can measure the mass loss as a function of temp

22
Q

thermomechanical analysis

A

measures dimensional change with or without an applied load

23
Q

glass transition temperature Tg

A

reversible transition in amorphous materials from a hard state to a more flexible state with increased temperature

24
Q

temperature of crystallization Tc

A

after a Tg, the amorphous material is less viscous, there may be a rearrangement of molecules into a crystalline state, resulting in an exothermic peak

25
melting temperature TM
with increased temperature, the sample reaches its melting point, resulting in an endothermic peak
26
differential scanning calorimetry (DSC)
used to locate transition temperatures and study effects on material
27
heat/enthalpy of fusion
the quantity of heat to convert 1g of a material from solid to liquid with no temperature change
28
thermal conductivity
the quantity of heat required per second to pass through 1 cm material with a cross sectional area of 1 cm2
29
metals have much _____ thermal conductivity than non-metals
higher
30
specific heat capacity
quantity of heat needed to raise the temperature of 1 gram of material one degree
31
relationship of metals and specific heat capacity
metals have low specific heat because they require less heat to warm also give up their heat quickly
32
thermal diffusivity
the rate of heat transfer through a medium significant difference between metal and ceramic values
33
coefficient of thermal expansion
the rate at which a material expands during temperature change
34
thermal expansion of restoration in tooth
no heat: restoration expands more than tooth, wedging and extrusion heat applied: restoration expands less than tooth, loosening and gap formation
35
electrical conductivity
the ability to conduct an electric current and is governed by Ohm's Law ceramics are not good conductors, called insulators
36
electrical resistivity
the resistance to passing electric current the resistivity of a homogenous conductor varies directly with its length and cross-sectional area
37
resistance and resistivity are proportional based on the
length and size of the material
38
dielectric material
provides electrical insulation but can be polarized in an electric field
39
electromotive force emf
metals and alloys used in dental restorations are susceptible to corrosion is a listing in order of their decreasing tendency to oxidize in solution
40
bimetallic corrosion/galvanism
two dissimilar filling materials in opposing teeth have a difference in emf the saliva can act as an electrolyte if the flow of current goes through the patients pulp, pain is experienced and the anodic restoration may corrode