Oils and fats Flashcards

1
Q

How much lipid is in seeds or fruits?

A

20-50% by weight

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2
Q

What is oil?

A

The energy reserve for germination

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3
Q

What can the residue from oil seeds be used for?

A

Animal feed as it is high in protein

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4
Q

Why are seeds easily transported and stored?

A

Because they have a low moisture content and won’t go off

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5
Q

What are the 2 methods for oil extraction from soya beans?

A

Direct solvent extraction and mechanical extraction

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6
Q

How can omega 3, 6 and 9 be identified in fatty acids?

A

Depending on where the double bond is on the carbon chain

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7
Q

What is the structure of erucic acid?

A

22 carbons with one double bond (22:1) at the 9th carbon (omega 9)

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8
Q

What are triacylglycerol’s?

A

Fats consisting of 3 fatty acids (2 right, 1 left) and a glycerol backbone

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9
Q

What are phospholipids?

A

Cause foaming during cooking and draw water into oil leading to hydrolysis and TAG molecules

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10
Q

How are phospholipids removed?

A

A process called degumming where they are hydrated and oil and water are separated using centrifugation

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11
Q

What is lecithin?

A

A hydratable phosphate used in the food and pharma industries

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12
Q

Why are fats and oils processed?

A
  • Shelf life
  • Eating quality
  • Appearance
  • Safety
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13
Q

What are the processes for fats and oils?

A
  • Rendering
  • Wet screw pressing
  • High pressure screw pressing
  • Pre-pressing solvent extraction
  • Direct solvent extraction
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14
Q

At what temperature does sterilization and digestion occur at in wet screw pressing?

A

Sterilization: 132°C
Digestion: 90°C

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15
Q

What is the process for soya bean extraction?

A
  • Beans are tempered at 24°C for 7-10 days
  • Cracking and dehulling reduces the impurities and increases protein
  • Conditioning at 60-80°C for 30-60 mins weakens the cell wall, reduces viscosity, coagulates proteins and sterilises seeds
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16
Q

Why is storage of crude oil important?

A

Because leaking, mixing and moisture can lead to rust or lipolysis

17
Q

Why is oil refined?

A
  • Removes contaminants
  • Maintains vitamin E
18
Q

What are the 3 processes for refining palm oil?

A

Pre-treatment (degumming), bleaching filtration and deodorization

19
Q

Emulsions

A

A mixture of one liquid with another which it cannot normally combine smoothly with

20
Q

2 examples of emulsions

A

Oil in water (mayonnaise) or water in oil (margarine)

21
Q

What is hydrophilic lipophilic balance (HLB)?

A

Value of a surfactant molecule

22
Q

How can HLB be calculated?

A

HLB= 20 x Mh/M
Mh=molecular mass of the hydrophilic portion of the molecule
M=molecular mass of the whole molecule

23
Q

How many carbons are in water soluble substances?

A

10 or more

24
Q

How many carbons are in water dispersible substances?

A

6-10

25
Q

How many carbons are in oil soluble substances?

A

6 or less

26
Q

What has a HLB value of 2.8-3.8?

A

Monoglycerides and diglycerides

27
Q

What is the HLB value of lecithin?

A

4-10

28
Q

What is the HLB value of triglycerides?

A

8-10

29
Q

Structure of fatty acids

A

R group and carboxylic group

30
Q

How is an ester made?

A

Carboxylic acid reacts with alcohol in a condensation reaction

31
Q

What are stereoisomers?

A

Isomers with the same bonded atoms but with different forms in space

32
Q

What are conformational isomers?

A

Stereoisomers which easily change forms around a single bond

33
Q

What are configurational isomers?

A

Stereoisomers which can’t change forms due to double bonds

34
Q

Cis vs trans isomers

A

Cis- 1 and 4 carbons on the same side of double bond
Trans- 1 and 4 carbons on different sides of double bond

35
Q

How do double bonds effect melting point?

A

More double bonds the lower the melting point as chain gets shorter