Ocean Acidification Flashcards
ionic product of water
2H2O <=> H3O+ + OH- ; 25 degrees, equal conc, equlibirium
why is water an amphiprotic substance?
it can donate and accept a proton
pH and pOH calculation
pH + pOH = 14
how does water acidify
more hydronium ions enter.
explanation: CO2 + H2O <=> H2CO3
carbon dioxide is soluble in the sea and reacts to carbonic acid.
explanation: H2CO3 + H2O <=> H3O+ + HCO3-
carbonic acid is weak and partially ionises into hydronium ions and hydrogen carbonate ions.
explanation: HCO3- + H2O <=> H3O + CO3
hydrogen carbonate ions further ionise in water, forming hydronium ions and carbonate ions.
how do hydronium ions affect alkanity?
the sea is naturally alkaline at pH 8.2, and a decrease by 0.1 represents a 30% increase in H+ concentration.
pH equation
pH = -log [H+]
[H+] equation
[H+] = 10^-pH mol/L
effect of ocean acidification on marine animals
metals and acid make carbon dioxide, water, and salt. shells made of calcium carbonate can dissolve in acid, ionic equation: CaCO3 + 2H+ –> CO2 + H2O + Ca2+. this depletes the habitats of shellfish, which also leads to shortage of food for humans.