O Chem 1 Reactions Flashcards
Tert-butoxide
Turns Br into a less substituted double bond
SOCl2
Turns OH into Cl
Substitution reaction
PBr3
Turns OH into Br
Substitution reaction
POCl3 and pyridine
Removes OH and makes DB
Elimination reaction
Alkene: H2 and Pdc
2 H’s add syn
Alkene: HX
X adds to more substituted carbon, syn or anti
Alkene: X2
X add to each DB carbon, syn or anti
Alkene: X2 and H2O
Oh adds to more sub and H adds to less sub
Alkene: OSO4 and NaHSO3
2 OH’s add syn
Alkene: O3
A ketone or aldehyde forms on each DB carbon
Alkene: H2O and H2SO4
OH forms on more sub carbon
Alkene: BH3, H2O2, KOH
OH forms on less sub carbon
Alkyne: H2 and Pdc
2 H’s on each carbon –> SB
Alkyne: H2 and Lindlar’s
TB –> DB H’s add syn
Alkyne: Na, NH3 or Li, NH3
TB –> DB H’s add anti