O Chem 1 Reactions Flashcards

1
Q

Tert-butoxide

A

Turns Br into a less substituted double bond

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2
Q

SOCl2

A

Turns OH into Cl

Substitution reaction

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3
Q

PBr3

A

Turns OH into Br

Substitution reaction

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4
Q

POCl3 and pyridine

A

Removes OH and makes DB

Elimination reaction

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5
Q

Alkene: H2 and Pdc

A

2 H’s add syn

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6
Q

Alkene: HX

A

X adds to more substituted carbon, syn or anti

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7
Q

Alkene: X2

A

X add to each DB carbon, syn or anti

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8
Q

Alkene: X2 and H2O

A

Oh adds to more sub and H adds to less sub

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9
Q

Alkene: OSO4 and NaHSO3

A

2 OH’s add syn

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10
Q

Alkene: O3

A

A ketone or aldehyde forms on each DB carbon

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11
Q

Alkene: H2O and H2SO4

A

OH forms on more sub carbon

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12
Q

Alkene: BH3, H2O2, KOH

A

OH forms on less sub carbon

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13
Q

Alkyne: H2 and Pdc

A

2 H’s on each carbon –> SB

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14
Q

Alkyne: H2 and Lindlar’s

A

TB –> DB H’s add syn

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15
Q

Alkyne: Na, NH3 or Li, NH3

A

TB –> DB H’s add anti

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16
Q

Alkyne: HX

A

2 X’s add to more sub carbon

17
Q

Alkyne: X2

A

2 X’s add to each TB carbon

18
Q

Alkyne: O3

A

Carboxylic acids form on each TB carbon

19
Q

Alkyne: H2O and H2SO4

A

Ketone forms on more sub carbon

20
Q

Alkyne: BH3, H2O2, KOH

A

Aldehyde forms on less sub carbon

21
Q

McPBA

A

Adds epoxide when OH and X are anti

22
Q

LAH

A

removes X

Removes OTs

Opens epoxide @ less sub carbon

23
Q

CrO3 and H2SO4 with alcohol

A

Primary alcohols –> carboxylic acids

Secondary/ tertiary alcohols –> ketones

24
Q

PCC with alcohol

A

OH becomes ketone or aldehyde

25
Q

NaH

A

Makes epoxide

*Deprotonates OH to add carbons

26
Q

NaNH2

A

*Deprontonates OH to add carbons

Makes TB from anti X’s