O- Aromatics =) Flashcards

1
Q

In practice, ethanoic anhydride is used in the industrial synthesis rather than ethanoyl chloride.
Give one reason why ethanoyl chloride is not used in the industrial synthesis. (1)

A

corrosive

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2
Q

ΔH of cyclohexene = -120kJmol-1
ΔH of benzene = -208kJmol-1
The enthalpy of hydrogenation of cyclohexa-1,3-diene is not exactly double that of cyclohexene.
Suggest a value for the enthalpy of hydrogenation of cyclohexa-1,3-diene and justify your value. (3)

A
  • betw. -239 & -121
  • double bonds separated by 1 single bond
  • ✔ some delocalisation/ overlap of p-orbitals
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3
Q

What is the role of HNO3 in:
HNO3 + 2H2SO4 –> NO2+ + H3O+ +2H2SO4
(1)

A

base

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