Nucleophiles, Electrophiles and Reaction Types Flashcards
1
Q
what are attacking groups classified as in reactions involving heterolytic bond fission?
A
nucleophiles or electrophiles
2
Q
what are nucleophiles?
A
- negatively charged ions or neutral molecules that are electron rich, such as:
Cl−, Br−, OH−, CN− , NH3 and H2O - attracted towards atoms bearing a partial (δ + ) or full positive charge
- capable of donating an electron pair to form a new covalent bond
3
Q
what are electrophiles?
A
- positively charged ions or neutral molecules that are electron deficient, such as:
H+, NO+ and SO3 - attracted towards atoms bearing a partial (δ − ) or full negative charge
- capable of accepting an electron pair to form a new covalent bond
4
Q
what reaction types can be identified from a chemical equation?
A
- substitution
- addition
- elimination
- condensation
- hydrolysis
- oxidation
- reduction
- neutralisation