Nuclear Chemistry Flashcards

1
Q

alpha decay

A
  • emission of an alpha particle consisting of 2 protons and 2 neutrons
  • helium nucleus
  • A = 4
  • Z = 2
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2
Q

beta decay

A
  • emission of an electron from the nucleus
  • A = 0
  • Z = 1
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3
Q

gamma decay

A
  • emissions of gamma particles which are high energy photons
  • A = 0
  • Z = 0
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4
Q

positron emission

A
  • emission of a positron from the nucleus
  • A = 0
  • Z = +1
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5
Q

fraction of nuclei remaining after n half lives

A

(1/2)^n

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6
Q

fraction of nuclei that has decayed after n half lives

A

1 - (1/2)^n

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7
Q

binding energy

A
  • negative energy of the electron bound to the nucleus
  • mass defect
  • BE = (deltam)c^2
  • the difference between the sum of the masses of the individual nucleons and the mass of the nucleus
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8
Q

values of energies at different levels n given in electron-volts

A

En = 13.6eV/(n^2)

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9
Q

radiation and absorption of light are caused by

A

transition of atomic electrons from one energy state to another

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10
Q

electrons jump form one energy state to another

A
  • must make discrete jumps

- must absorb or emit a photon of equal energy

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11
Q

energy of a photon

A

E = hf

  • photon emission (E < 0)
  • photon absorption (E > 0)
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12
Q

nuclear half life

A
  • population of radioactive nuclei will decay at an exponential rate
  • N = N0e^-tlamda
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13
Q

half life

A

T1/2 = .693/lamda

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