Nomenclature Flashcards

1
Q

of carbons in the main chain prefixes

A

meth, eth, prop, but, pent, hex, hept, oct, non, dec

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2
Q

meth-

A

1 carbon

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3
Q

eth-

A

2 carbons

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4
Q

prop-

A

3 carbons

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5
Q

but-

A

four carbons

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6
Q

pent-

A

5 carbons

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7
Q

hex-

A

6 carbons

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8
Q

hept-

A

seven carbons

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9
Q

oct-

A

8 carbons

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10
Q

non-

A

9 carbons

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11
Q

dec-

A

10 carbons

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12
Q

Naming an unbranched alkane

A

of Carbons prefix + ane

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13
Q

-Ane

A

refers to alkane

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14
Q

Naming a branched alkane

A
  1. Find the longest continuous chain
  2. Number each substituent so that the substituent has lowest carbon number
  3. Find the carbon that the substituent goes off of
  4. Put carbon number substituent goes off of + substituent + root name together
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15
Q

Substituent

A

attached to main chain, branch

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16
Q

Common substituent names

A

methyl, ethyl, propyl, isopropyl, butyl, isobutyl, secbutyl, tertbutyl

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17
Q

Methyl

A

CH3

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18
Q

Ethyl

A

CH2CH3

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19
Q

Propyl

A

CH2CH2CH3

20
Q

Butyl

A

CH2CH2CH2CH3

21
Q

Isopropyl

A

looks like fork or antibody structure

22
Q

Isobutyl

A

has CH2 before going into antibody structure

23
Q

tert-butyl

A

looks like a chicken stick claw

24
Q

sec-butyl

A

looks like an antibody attached to an antigen on one end

25
Q

Dashes

A

separate numbers and letters

26
Q

commas

A

separate numbers only

27
Q

2 or more substituents present in molecule

A

Number in a way so that the substituent that occurs first gets the lowest number

28
Q

What do di-, tri-, tetra-, penta-, and hexa- denote?

A

they denote the number of a certain type of substituent (substituent is the same in the different areas its found in) in a molecule

29
Q

2 or more different substituents present in molecule

A
  1. List in alphabetical order
  2. Number the chain in a way that gives the lowest carbon number to the 1st substituent encountered
30
Q

what happens if both different substituents are encountered at the same time?

A

Go alphabetically then

31
Q

Di-, tri-, tetra-, penta-, hexa-

A

not included in alphabetizing when it comes to the 2 or more different substituents situation

32
Q

2 or more main chains have the same length

A

Choose the main chain with more substituents

33
Q

Cycloalkanes

A

alkane joined in a ring

34
Q

Cyclopropane

A

triangle-like structure, 3-carbon

35
Q

Cyclobutane

A

square-like structure, 4-carbon

36
Q

Cyclopentane

A

pentagon-like structure, 5-carbon

37
Q

Cycloalkanes with 1 substituent

A

no carbon number in front of substituent name e.g. methylcyclopentane

38
Q

Cycloalkanes with 2 substitiuents

A
  1. number the carbons to where you get to the substituents in the lowest possible number of carbons but do this alphabetically
    e.g. if you have an ethyl and a methyl substituent, then start numbering at the ethyl since E is first in the alphabet, but make sure to number so that you get to the methyl group through the shortest path of carbons
39
Q

Cycloalkanes with 3 substituents

A
  1. Number substituents so that the sum of the numbers is the lowest possible
  2. List the substituents in alphabetical order
40
Q

Alcohol suffix

A

-ol

41
Q

Alkyne suffix

A

-yne

42
Q

Alkene suffix

A

-ene

43
Q

Alkyl halide

A

The halogen of an alkyl halide is treated as a substituent on an alkane chain. Listed alphabetically since different substituent
e.g. chloro-, fluro-, bromo-, iodo-, etc (Replace the-ine with an o)

44
Q

Alkene + Alcohol

A

Alcohol has priority–>-ol is used; carbon number of where the double bond starts followed by the prefix “en-“,

45
Q

Alkenes + Alkyl Halides

A

Alkyl halide will be a prefix; alkene will take priority (-ene)

46
Q

Alkyne +Alkyl Halides

A

Alkyne takes priority, halide will be prefix

47
Q

Alkynes + Alcohols

A

Alcohol takes priority (end with -ol); carbon number of where triple bond start followed by -yn will be prefix.