Nitrogen Cycle Flashcards
What does soil N decrease with?
Average soil temperature increase, decreasing by 2-3x every 10C rise due to increasing microbial activity
Why does permanent grass vegetation have higher N content than forests?
Dense rhizosphere promoting humus formation thus N immobilization
What are organic forms of nitrogen in soils?
Proteins, nucleic acids, chitin, peptidoglycan and amino acids
When might organic nitrogen be unavaialble?
Restrictired to inaccessible micropores or binding to clay
Urea decomposers…
Urease secreted as an extracellular enzyme, being 32-69% of bacterial production being urea-decomposers
Why might Urea be bad for soils?
Hydrolysis consuming H and increasing pH, where ammonia can volatise at high pH
How might NH4 be made available to plants?
Involved in CEC or immobilised by interlayers of clays
What is nitrification performed by?
Chemoautotrophs and heterotrophs, being oxidation of NH4 and organic N into NO2 and NO3
Which chemoautotrophs perform nitrification?
Nitrobacter, nitrosomonas, nitrosolobus
What is the process of chemoautotroph nitrification?
O2, H and NH4 required for NO2 formation with NH4 deprotonation to ammonia then oxidation to hydroxylamine, then nitroxyl formation then nitrite formation
Requirements of nitrification…
Obligatory aerobic, requires O2 supply, optimal temperature range of 5-40, neutral-alklaline soils
What can abundant nitrification lead to?
Eutrophication, nitrosamine formation and methemoglobnemia in animals
How can NO3 be limited?
Slow-release fertilisers, like sulfur-coated urea: limits NH4 availabilit rate to nitrifiers
How might nitrogen be immobilised?
Microorganism fixation or NH4 ion assimilation into glutamate
How can Inorganic N be assimilated as NO3?
Reduction into NO2, NH4 depending on Mb cofactor