Nitrogen and Sulfur Flashcards

1
Q

What percentage of air is Nitrogen?

A

78%

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2
Q

Why is nitrogen so inert?

A

Due to the triple diatomic covalent bond between the molecules

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3
Q

Which process produces ammonia?

A

Haber process

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4
Q

Write an equation for the haber process

A

N2(g) + 3H2(g) ⇌ 2NH3(g)

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5
Q

Write the dissociation of ammonia in water

A

NH3(aq) + H2O(l) ⇌ NH4+(aq) + OH-(aq)

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6
Q

What is the shape of ammonia molecule?

A

Pyramidal

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7
Q

What is the shape of a ammonium molecule?

A

Tetrahedral

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8
Q

Give an example of an acid-base reaction that produces ammonia

A

(an ammonium salt and a base) 2NH4Cl (s) + Ca(OH)2 (s) –> CaCl2 (s) + 2H2O (l) + 2NH3 (g)

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9
Q

How can nitrogen dioxide be reduced back to nitrogen?

A

By reacting with carbon monoxide on the surface of catalytic converters

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10
Q

Why are nitrogen dioxides primary polluters?

A

Because they are given off directly into the air from the source of pollution.

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11
Q

What are two examples of sources of pollution?

A

car exhausts and power plants

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12
Q

What does VOC stand for?

A

volatile organic compound

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13
Q

What is the product of the reaction of VOCs with nitrogen dioxide?

A

peroxyacetyl nitrate (PAN)

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14
Q

what conditions are needed for the reaction between VOCs and nitrogen dioxide to occur?

A

Sunlight (its a photochemical reaction)

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15
Q

What is an example of harmful pollutants found in smog?

A

peroxyacetyl nitrate (PAN)

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16
Q

What does PAN affect?

A

lungs, eyes and plantlife

17
Q

What is the equation which shows the production of acid rain using nitrogen dioxide?

A

NO2(aq) + H2O(l) + 1½O2(g) → 2HNO3(aq)

18
Q

In which reaction do nitrogen oxides act as a catalyst and write down both reactions.

A

Reaction of conversion of sulfur dioxide to sulfur trioxide:
NO2(g) + SO2(g) → SO3(g) + NO(g)
then right after:
NO(g) + ½ O2(g) → NO2(g)

19
Q

What is the equation of formation of ammonium nitrate

A

HNO3 + NH3 -> NH4NO

20
Q

What is the bond angle and name of ammonia?

A

107 degrees, trigonal pyramidal

21
Q

What type of species would decrease the effectiveness of ammonia chloride as a fertilizer?

A

Bases

22
Q

What is the formula of ammonium sulphate?

A

(NH4)2SO4